Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine

Satoshi Iwashita; Yoshiaki Saito; Hideki Ohtsu; Kiyoshi Tsuge

doi:10.1039/c4dt02279c

Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine

Satoshi Iwashita, Yoshiaki Saito, Hideki Ohtsu, Kiyoshi Tsuge^*

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

6 被引用数 (Scopus)

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Three gold(iii) complexes with terminal amido ligands were prepared by the reaction of [Au^III(trpy)(OH)](ClO₄)₂ and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.

本文言語	英語
ページ（範囲）	15719-15722
ページ数	4
ジャーナル	Dalton Transactions
巻	43
号	42
DOI	https://doi.org/10.1039/c4dt02279c
出版ステータス	出版済み - 2014/11/14

ASJC Scopus 主題領域

無機化学

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10.1039/c4dt02279c

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title = "Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine",

abstract = "Three gold(iii) complexes with terminal amido ligands were prepared by the reaction of [AuIII(trpy)(OH)](ClO4)2 and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.",

author = "Satoshi Iwashita and Yoshiaki Saito and Hideki Ohtsu and Kiyoshi Tsuge",

note = "Publisher Copyright: {\textcopyright} the Partner Organisations 2014.",

year = "2014",

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doi = "10.1039/c4dt02279c",

language = "英語",

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TY - JOUR

T1 - Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine

AU - Iwashita, Satoshi

AU - Saito, Yoshiaki

AU - Ohtsu, Hideki

AU - Tsuge, Kiyoshi

PY - 2014/11/14

Y1 - 2014/11/14

N2 - Three gold(iii) complexes with terminal amido ligands were prepared by the reaction of [AuIII(trpy)(OH)](ClO4)2 and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.

AB - Three gold(iii) complexes with terminal amido ligands were prepared by the reaction of [AuIII(trpy)(OH)](ClO4)2 and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84908360974&partnerID=8YFLogxK

U2 - 10.1039/c4dt02279c

DO - 10.1039/c4dt02279c

M3 - 学術論文

C2 - 25247831

AN - SCOPUS:84908360974

SN - 1477-9226

VL - 43

SP - 15719

EP - 15722

JO - Dalton Transactions

JF - Dalton Transactions

IS - 42

ER -

Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine

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