Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine

Satoshi Iwashita; Yoshiaki Saito; Hideki Ohtsu; Kiyoshi Tsuge

doi:10.1039/c4dt02279c

Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine

Satoshi Iwashita, Yoshiaki Saito, Hideki Ohtsu, Kiyoshi Tsuge^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Three gold(iii) complexes with terminal amido ligands were prepared by the reaction of [Au^III(trpy)(OH)](ClO₄)₂ and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.

Original language	English
Pages (from-to)	15719-15722
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	42
DOIs	https://doi.org/10.1039/c4dt02279c
State	Published - 2014/11/14

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine",

abstract = "Three gold(iii) complexes with terminal amido ligands were prepared by the reaction of [AuIII(trpy)(OH)](ClO4)2 and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.",

author = "Satoshi Iwashita and Yoshiaki Saito and Hideki Ohtsu and Kiyoshi Tsuge",

note = "Publisher Copyright: {\textcopyright} the Partner Organisations 2014.",

year = "2014",

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doi = "10.1039/c4dt02279c",

language = "英語",

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T1 - Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine

AU - Iwashita, Satoshi

AU - Saito, Yoshiaki

AU - Ohtsu, Hideki

AU - Tsuge, Kiyoshi

PY - 2014/11/14

Y1 - 2014/11/14

N2 - Three gold(iii) complexes with terminal amido ligands were prepared by the reaction of [AuIII(trpy)(OH)](ClO4)2 and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.

AB - Three gold(iii) complexes with terminal amido ligands were prepared by the reaction of [AuIII(trpy)(OH)](ClO4)2 and primary amines having electron-withdrawing groups such as 2-amino-4-chloropyrimidine, 2-amino-5-chloro-pyridine, and 2-aminopyrimidine. Conversion of the amido ligands into the imido or amine ligands resulted in the decomposition of the complexes by intramolecular redox reaction or the release of amine ligands, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84908360974&partnerID=8YFLogxK

U2 - 10.1039/c4dt02279c

DO - 10.1039/c4dt02279c

M3 - 学術論文

C2 - 25247831

AN - SCOPUS:84908360974

SN - 1477-9226

VL - 43

SP - 15719

EP - 15722

JO - Dalton Transactions

JF - Dalton Transactions

IS - 42

ER -

Synthesis, structures and stability of amido gold(iii) complexes with 2,2′:6′,2′′-terpyridine

Abstract

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