Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex

Hideki Ohtsu; Kiyoshi Tsuge; Koji Tanaka

doi:10.1016/j.jphotochem.2015.05.011

Remarkable accelerating and decelerating effects of the bases on CO₂ reduction using a ruthenium NADH model complex

Hideki Ohtsu^*, Kiyoshi Tsuge, Koji Tanaka

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

11 被引用数 (Scopus)

抄録

Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)₂(pbnHH)](PF6)₂ (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.

本文言語	英語
ページ（範囲）	163-167
ページ数	5
ジャーナル	Journal of Photochemistry and Photobiology A: Chemistry
巻	313
DOI	https://doi.org/10.1016/j.jphotochem.2015.05.011
出版ステータス	出版済み - 2015/12/01

ASJC Scopus 主題領域

化学一般
化学工学一般
物理学および天文学一般

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10.1016/j.jphotochem.2015.05.011

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title = "Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex",

abstract = "Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)2(pbnHH)](PF6)2 (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.",

keywords = "Carbon dioxide reduction, NAD model ligands, Organic hydride, Ruthenium complex, transfer",

author = "Hideki Ohtsu and Kiyoshi Tsuge and Koji Tanaka",

year = "2015",

month = dec,

day = "1",

doi = "10.1016/j.jphotochem.2015.05.011",

language = "英語",

volume = "313",

pages = "163--167",

journal = "Journal of Photochemistry and Photobiology A: Chemistry",

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T1 - Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex

AU - Ohtsu, Hideki

AU - Tsuge, Kiyoshi

AU - Tanaka, Koji

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)2(pbnHH)](PF6)2 (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.

AB - Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)2(pbnHH)](PF6)2 (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.

KW - Carbon dioxide reduction

KW - NAD model ligands

KW - Organic hydride

KW - Ruthenium complex

KW - transfer

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U2 - 10.1016/j.jphotochem.2015.05.011

DO - 10.1016/j.jphotochem.2015.05.011

M3 - 学術論文

AN - SCOPUS:84944442122

SN - 1010-6030

VL - 313

SP - 163

EP - 167

JO - Journal of Photochemistry and Photobiology A: Chemistry

JF - Journal of Photochemistry and Photobiology A: Chemistry

ER -

Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex

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ASJC Scopus 主題領域

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引用スタイル

Remarkable accelerating and decelerating effects of the bases on CO₂ reduction using a ruthenium NADH model complex