Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex

Hideki Ohtsu; Kiyoshi Tsuge; Koji Tanaka

doi:10.1016/j.jphotochem.2015.05.011

Remarkable accelerating and decelerating effects of the bases on CO₂ reduction using a ruthenium NADH model complex

Hideki Ohtsu^*, Kiyoshi Tsuge, Koji Tanaka

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)₂(pbnHH)](PF6)₂ (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.

Original language	English
Pages (from-to)	163-167
Number of pages	5
Journal	Journal of Photochemistry and Photobiology A: Chemistry
Volume	313
DOIs	https://doi.org/10.1016/j.jphotochem.2015.05.011
State	Published - 2015/12/01

Keywords

Carbon dioxide reduction
NAD model ligands
Organic hydride
Ruthenium complex
transfer

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
General Physics and Astronomy

Access to Document

10.1016/j.jphotochem.2015.05.011

Cite this

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title = "Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex",

abstract = "Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)2(pbnHH)](PF6)2 (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.",

keywords = "Carbon dioxide reduction, NAD model ligands, Organic hydride, Ruthenium complex, transfer",

author = "Hideki Ohtsu and Kiyoshi Tsuge and Koji Tanaka",

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doi = "10.1016/j.jphotochem.2015.05.011",

language = "英語",

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T1 - Remarkable accelerating and decelerating effects of the bases on CO2 reduction using a ruthenium NADH model complex

AU - Ohtsu, Hideki

AU - Tsuge, Kiyoshi

AU - Tanaka, Koji

PY - 2015/12/1

Y1 - 2015/12/1

N2 - Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)2(pbnHH)](PF6)2 (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.

AB - Successful control over the rate of the organic hydride transfer reaction converting carbon dioxide to formate using a ruthenium NADH model complex, [Ru(bpy)2(pbnHH)](PF6)2 (bpy = 2,2′-bipyridine, pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b][1,5]naphthyridine) has been accomplished by the tuning of the basicity of the bases. The base adduct being found to be the key compound in the carbon dioxide reduction has been fully characterized through various physicochemical methods.

KW - Carbon dioxide reduction

KW - NAD model ligands

KW - Organic hydride

KW - Ruthenium complex

KW - transfer

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