Erratum: Corrected Structure of Natural Hyacinthacine C1 via Total Synthesis (Journal of Natural Products (2019) 82: 2 (358−367) DOI: 10.1021/acs.jnatprod.8b00879)

Anthony W. Carroll, Anthony C. Willis, Masako Hoshino, Atsushi Kato, Stephen G. Pyne*

*Corresponding author for this work

Research output: Contribution to journalComment/debate

Abstract

Metrics & More. Article Recommendations. Page 365, For the synthesis of (3aR,4R,6R,7R,8S,8aS,8bS)-7,8-Bisbenzyloxy-6-[(benzyloxy)-methyl]-4-methylhexahydro-4H-[1,3,2]dioxathiolo[4,5-a]-pyrrolizine 2,2-dioxide (26), the reagent SOCl2 should be replaced by SO2Cl2. This reagent (SO2Cl2) is correctly shown in the Scheme. The correct text is: (3aR,4R,6R,7R,8S,8aS,8bS)-7,8-Bisbenzyloxy-6-[(benzyloxy)-methyl]-4-methylhexahydro-4H-[1,3,2]dioxathiolo[4,5-a]-pyrrolizine 2,2-dioxide (26). To a solution of the diol 25 (25 mg, 0.0511 mmol) in anhydrous CH2Cl2 (5 mL) under a nitrogen atmosphere was added at 0 °C Et3 N (18 μL, 0.128 mmol), then SO2Cl2 (1.0 M solution in CH2Cl2, 0.0766 μL, 0.0766 mmol) dropwise.

Original languageEnglish
Pages (from-to)1733
Number of pages1
JournalJournal of Natural Products
Volume83
Issue number5
DOIs
StatePublished - 2020/05/22

ASJC Scopus subject areas

  • Analytical Chemistry
  • Molecular Medicine
  • Pharmacology
  • Pharmaceutical Science
  • Drug Discovery
  • Complementary and alternative medicine
  • Organic Chemistry

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