Wavelength of luminescence and energy level structure of binuclear copper(I) complex

Tomohiko Ishii; Masahiro Kenmotsu; Kiyoshi Tsuge; Genta Sakane; Yoichi Sasaki; Masahiro Yamashita; Brian K. Breedlove

doi:10.1007/978-3-319-11185-8_14

Wavelength of luminescence and energy level structure of binuclear copper(I) complex

Tomohiko Ishii^*, Masahiro Kenmotsu, Kiyoshi Tsuge, Genta Sakane, Yoichi Sasaki, Masahiro Yamashita, Brian K. Breedlove

^*この論文の責任著者

化学科

研究成果: 書籍の章/レポート/会議録 › 章 › 査読

抄録

We investigate the mechanism of strong fluorescence and phosphorescence observed in the binuclear copper complexes by means of a discrete variational (DV)-Xα molecular orbital calculation. Comparing to the energy differences among a occupied and unoccupied molecular orbitals, we can reveal the photon energy of the light of the luminescence in a quantitative way. We also obtained the strong relationship between the observed and the calculated photon energies with according to the conservation of energy principle.

本文言語	英語
ホスト出版物のタイトル	The DV-X Molecular-Orbital Calculation Method
出版社	Springer International Publishing
ページ	333-357
ページ数	25
ISBN（電子版）	9783319111858
ISBN（印刷版）	9783319111841
DOI	https://doi.org/10.1007/978-3-319-11185-8_14
出版ステータス	出版済み - 2015/01/01

ASJC Scopus 主題領域

化学一般
工学一般
材料科学一般

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10.1007/978-3-319-11185-8_14

引用スタイル

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author = "Tomohiko Ishii and Masahiro Kenmotsu and Kiyoshi Tsuge and Genta Sakane and Yoichi Sasaki and Masahiro Yamashita and Breedlove, {Brian K.}",

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AU - Ishii, Tomohiko

AU - Kenmotsu, Masahiro

AU - Tsuge, Kiyoshi

AU - Sakane, Genta

AU - Sasaki, Yoichi

AU - Yamashita, Masahiro

AU - Breedlove, Brian K.

PY - 2015/1/1

Y1 - 2015/1/1

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AB - We investigate the mechanism of strong fluorescence and phosphorescence observed in the binuclear copper complexes by means of a discrete variational (DV)-Xα molecular orbital calculation. Comparing to the energy differences among a occupied and unoccupied molecular orbitals, we can reveal the photon energy of the light of the luminescence in a quantitative way. We also obtained the strong relationship between the observed and the calculated photon energies with according to the conservation of energy principle.

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PB - Springer International Publishing

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Wavelength of luminescence and energy level structure of binuclear copper(I) complex

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