Wavelength of luminescence and energy level structure of binuclear copper(I) complex

Tomohiko Ishii; Masahiro Kenmotsu; Kiyoshi Tsuge; Genta Sakane; Yoichi Sasaki; Masahiro Yamashita; Brian K. Breedlove

doi:10.1007/978-3-319-11185-8_14

Wavelength of luminescence and energy level structure of binuclear copper(I) complex

Tomohiko Ishii^*, Masahiro Kenmotsu, Kiyoshi Tsuge, Genta Sakane, Yoichi Sasaki, Masahiro Yamashita, Brian K. Breedlove

^*Corresponding author for this work

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

We investigate the mechanism of strong fluorescence and phosphorescence observed in the binuclear copper complexes by means of a discrete variational (DV)-Xα molecular orbital calculation. Comparing to the energy differences among a occupied and unoccupied molecular orbitals, we can reveal the photon energy of the light of the luminescence in a quantitative way. We also obtained the strong relationship between the observed and the calculated photon energies with according to the conservation of energy principle.

Original language	English
Title of host publication	The DV-X Molecular-Orbital Calculation Method
Publisher	Springer International Publishing
Pages	333-357
Number of pages	25
ISBN (Electronic)	9783319111858
ISBN (Print)	9783319111841
DOIs	https://doi.org/10.1007/978-3-319-11185-8_14
State	Published - 2015/01/01

ASJC Scopus subject areas

General Chemistry
General Engineering
General Materials Science

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abstract = "We investigate the mechanism of strong fluorescence and phosphorescence observed in the binuclear copper complexes by means of a discrete variational (DV)-Xα molecular orbital calculation. Comparing to the energy differences among a occupied and unoccupied molecular orbitals, we can reveal the photon energy of the light of the luminescence in a quantitative way. We also obtained the strong relationship between the observed and the calculated photon energies with according to the conservation of energy principle.",

author = "Tomohiko Ishii and Masahiro Kenmotsu and Kiyoshi Tsuge and Genta Sakane and Yoichi Sasaki and Masahiro Yamashita and Breedlove, {Brian K.}",

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AU - Ishii, Tomohiko

AU - Kenmotsu, Masahiro

AU - Tsuge, Kiyoshi

AU - Sakane, Genta

AU - Sasaki, Yoichi

AU - Yamashita, Masahiro

AU - Breedlove, Brian K.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - We investigate the mechanism of strong fluorescence and phosphorescence observed in the binuclear copper complexes by means of a discrete variational (DV)-Xα molecular orbital calculation. Comparing to the energy differences among a occupied and unoccupied molecular orbitals, we can reveal the photon energy of the light of the luminescence in a quantitative way. We also obtained the strong relationship between the observed and the calculated photon energies with according to the conservation of energy principle.

AB - We investigate the mechanism of strong fluorescence and phosphorescence observed in the binuclear copper complexes by means of a discrete variational (DV)-Xα molecular orbital calculation. Comparing to the energy differences among a occupied and unoccupied molecular orbitals, we can reveal the photon energy of the light of the luminescence in a quantitative way. We also obtained the strong relationship between the observed and the calculated photon energies with according to the conservation of energy principle.

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BT - The DV-X Molecular-Orbital Calculation Method

PB - Springer International Publishing

ER -

Wavelength of luminescence and energy level structure of binuclear copper(I) complex

Abstract

ASJC Scopus subject areas

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