Total Synthesis of Discorhabdin C: A General Aza Spiro Dienone Formation from O-Silylated Phenol Derivatives Using a Hypervalent Iodine Reagent

Keyphrases

• Total Synthesis 100%
• Phenol Derivatives 100%
• Spiro 100%
• Hypervalent Iodine Reagents 100%
• Discorhabdin 100%
• Dienones 100%
• Good Yield 50%
• New Zealand 50%
• First Total Synthesis 50%
• 2,2,2-Trifluoroethanol 50%
• Hypervalent Iodine Oxidation 50%
• Aminonaphthoquinone 50%
• Para-position 50%
• Bocage 50%
• Latrunculia 50%

Chemistry

• Hypervalence 100%
• formation 100%
• Phenol 100%
• 2,2,2-trifluoroethanol 50%