Synthetic studies on pyrroloindolizidine skeleton based on gold-catalyzed hydroamination-enamine cyclization-ring-closing metathesis strategy

Kenji Sugimoto; Natsumi Matsuo; Daisuke Tominaga; Yuji Matsuya

doi:10.3987/COM-18-S(F)56

Synthetic studies on pyrroloindolizidine skeleton based on gold-catalyzed hydroamination-enamine cyclization-ring-closing metathesis strategy

Kenji Sugimoto, Natsumi Matsuo, Daisuke Tominaga, Yuji Matsuya^*

^*この論文の責任著者

薬品製造学研究室

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

抄録

A pyrroloindolizidine skeleton, which is observed in myrmicarin alkaloids isolated from African ant, is highly unique, oligocyclic indolizidine derivative. We describe here an attempt on a synthesis of a pyrroloindolizidine skeleton with our originally developed gold-catalyzed cascade reaction and a newly developed synthetic route for the skeleton via gold-catalyzed hydroamination-enamine cyclization-ring-closing metathesis.

本文言語	英語
ページ（範囲）	875-890
ページ数	16
ジャーナル	Heterocycles
巻	99
号	2
DOI	https://doi.org/10.3987/COM-18-S(F)56
出版ステータス	出版済み - 2019

ASJC Scopus 主題領域

分析化学
薬理学
有機化学

文献へのアクセス

10.3987/COM-18-S(F)56

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引用スタイル

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title = "Synthetic studies on pyrroloindolizidine skeleton based on gold-catalyzed hydroamination-enamine cyclization-ring-closing metathesis strategy",

abstract = "A pyrroloindolizidine skeleton, which is observed in myrmicarin alkaloids isolated from African ant, is highly unique, oligocyclic indolizidine derivative. We describe here an attempt on a synthesis of a pyrroloindolizidine skeleton with our originally developed gold-catalyzed cascade reaction and a newly developed synthetic route for the skeleton via gold-catalyzed hydroamination-enamine cyclization-ring-closing metathesis.",

author = "Kenji Sugimoto and Natsumi Matsuo and Daisuke Tominaga and Yuji Matsuya",

note = "Publisher Copyright: {\textcopyright} 2019 The Japan Institute of Heterocyclic Chemistry Received",

year = "2019",

doi = "10.3987/COM-18-S(F)56",

language = "英語",

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AU - Sugimoto, Kenji

AU - Matsuo, Natsumi

AU - Tominaga, Daisuke

AU - Matsuya, Yuji

PY - 2019

Y1 - 2019

N2 - A pyrroloindolizidine skeleton, which is observed in myrmicarin alkaloids isolated from African ant, is highly unique, oligocyclic indolizidine derivative. We describe here an attempt on a synthesis of a pyrroloindolizidine skeleton with our originally developed gold-catalyzed cascade reaction and a newly developed synthetic route for the skeleton via gold-catalyzed hydroamination-enamine cyclization-ring-closing metathesis.

AB - A pyrroloindolizidine skeleton, which is observed in myrmicarin alkaloids isolated from African ant, is highly unique, oligocyclic indolizidine derivative. We describe here an attempt on a synthesis of a pyrroloindolizidine skeleton with our originally developed gold-catalyzed cascade reaction and a newly developed synthetic route for the skeleton via gold-catalyzed hydroamination-enamine cyclization-ring-closing metathesis.

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U2 - 10.3987/COM-18-S(F)56

DO - 10.3987/COM-18-S(F)56

M3 - 学術論文

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SN - 0385-5414

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JO - Heterocycles

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