Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates

Takayuki Yakura; Seiji Yamada; Akiharu Ueki; Masazumi Ikeda

doi:10.1055/s-1997-749

Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates

Takayuki Yakura, Seiji Yamada, Akiharu Ueki, Masazumi Ikeda^*

^*この論文の責任著者

分子合成化学研究室

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

11 被引用数 (Scopus)

抄録

Dirhodium(II)-catalyzed intramolecular C-H insertion reaction of 5-(tert-butyldimethylsilyloxy)-2-diazo-3-oxoalkanoates in dichloromethane at room temperature gave stereoselectively 2,3-cis-2- alkyl-3-(tert-butyldimethylsilyloxy)-5-oxocyclopentanecarboxylates.

本文言語	英語
ページ（範囲）	185-186
ページ数	2
ジャーナル	Synlett
巻	1997
号	2
DOI	https://doi.org/10.1055/s-1997-749
出版ステータス	出版済み - 1997

ASJC Scopus 主題領域

有機化学

文献へのアクセス

10.1055/s-1997-749

フィンガープリント

「Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{06d19d63d00c4013b7aa8dd2a397c2aa,

title = "Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates",

abstract = "Dirhodium(II)-catalyzed intramolecular C-H insertion reaction of 5-(tert-butyldimethylsilyloxy)-2-diazo-3-oxoalkanoates in dichloromethane at room temperature gave stereoselectively 2,3-cis-2- alkyl-3-(tert-butyldimethylsilyloxy)-5-oxocyclopentanecarboxylates.",

author = "Takayuki Yakura and Seiji Yamada and Akiharu Ueki and Masazumi Ikeda",

year = "1997",

doi = "10.1055/s-1997-749",

language = "英語",

volume = "1997",

pages = "185--186",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "2",

}

Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates. / Yakura, Takayuki; Yamada, Seiji; Ueki, Akiharu その他.
In: Synlett, Vol. 1997, No. 2, 1997, p. 185-186.

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

TY - JOUR

T1 - Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates

AU - Yakura, Takayuki

AU - Yamada, Seiji

AU - Ueki, Akiharu

AU - Ikeda, Masazumi

PY - 1997

Y1 - 1997

N2 - Dirhodium(II)-catalyzed intramolecular C-H insertion reaction of 5-(tert-butyldimethylsilyloxy)-2-diazo-3-oxoalkanoates in dichloromethane at room temperature gave stereoselectively 2,3-cis-2- alkyl-3-(tert-butyldimethylsilyloxy)-5-oxocyclopentanecarboxylates.

AB - Dirhodium(II)-catalyzed intramolecular C-H insertion reaction of 5-(tert-butyldimethylsilyloxy)-2-diazo-3-oxoalkanoates in dichloromethane at room temperature gave stereoselectively 2,3-cis-2- alkyl-3-(tert-butyldimethylsilyloxy)-5-oxocyclopentanecarboxylates.

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U2 - 10.1055/s-1997-749

DO - 10.1055/s-1997-749

M3 - 学術論文

AN - SCOPUS:0041801189

SN - 0936-5214

VL - 1997

SP - 185

EP - 186

JO - Synlett

JF - Synlett

IS - 2

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