Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates

Takayuki Yakura; Seiji Yamada; Akiharu Ueki; Masazumi Ikeda

doi:10.1055/s-1997-749

Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates

Takayuki Yakura, Seiji Yamada, Akiharu Ueki, Masazumi Ikeda^*

^*Corresponding author for this work

Synthetic and Biomolecular Organic Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Dirhodium(II)-catalyzed intramolecular C-H insertion reaction of 5-(tert-butyldimethylsilyloxy)-2-diazo-3-oxoalkanoates in dichloromethane at room temperature gave stereoselectively 2,3-cis-2- alkyl-3-(tert-butyldimethylsilyloxy)-5-oxocyclopentanecarboxylates.

Original language	English
Pages (from-to)	185-186
Number of pages	2
Journal	Synlett
Volume	1997
Issue number	2
DOIs	https://doi.org/10.1055/s-1997-749
State	Published - 1997

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Organic Chemistry

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@article{06d19d63d00c4013b7aa8dd2a397c2aa,

title = "Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates",

abstract = "Dirhodium(II)-catalyzed intramolecular C-H insertion reaction of 5-(tert-butyldimethylsilyloxy)-2-diazo-3-oxoalkanoates in dichloromethane at room temperature gave stereoselectively 2,3-cis-2- alkyl-3-(tert-butyldimethylsilyloxy)-5-oxocyclopentanecarboxylates.",

author = "Takayuki Yakura and Seiji Yamada and Akiharu Ueki and Masazumi Ikeda",

year = "1997",

doi = "10.1055/s-1997-749",

language = "英語",

volume = "1997",

pages = "185--186",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "2",

}

TY - JOUR

T1 - Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates

AU - Yakura, Takayuki

AU - Yamada, Seiji

AU - Ueki, Akiharu

AU - Ikeda, Masazumi

PY - 1997

Y1 - 1997

N2 - Dirhodium(II)-catalyzed intramolecular C-H insertion reaction of 5-(tert-butyldimethylsilyloxy)-2-diazo-3-oxoalkanoates in dichloromethane at room temperature gave stereoselectively 2,3-cis-2- alkyl-3-(tert-butyldimethylsilyloxy)-5-oxocyclopentanecarboxylates.

AB - Dirhodium(II)-catalyzed intramolecular C-H insertion reaction of 5-(tert-butyldimethylsilyloxy)-2-diazo-3-oxoalkanoates in dichloromethane at room temperature gave stereoselectively 2,3-cis-2- alkyl-3-(tert-butyldimethylsilyloxy)-5-oxocyclopentanecarboxylates.

UR - http://www.scopus.com/inward/record.url?scp=0041801189&partnerID=8YFLogxK

U2 - 10.1055/s-1997-749

DO - 10.1055/s-1997-749

M3 - 学術論文

AN - SCOPUS:0041801189

SN - 0936-5214

VL - 1997

SP - 185

EP - 186

JO - Synlett

JF - Synlett

IS - 2

ER -

Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates using Dirhodium(II)-catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5-silyloxyalkanoates

Abstract

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