TY - JOUR
T1 - Novel synthesis of a four-electron-reduced ruthenium(II) NADH-type complex under water-gas-shift reaction conditions
AU - Ohtsu, Hideki
AU - Fujii, Sho
AU - Tsuge, Kiyoshi
AU - Tanaka, Koji
N1 - Publisher Copyright:
© 2016 Royal Society of Chemistry.
PY - 2016
Y1 - 2016
N2 - A four-electron-reduced ruthenium(ii) NADH-type complex, [Ru(bbnpH4)(CO)2Cl](PF6) (bbnpH4 = 2,2′-(4-(tert-butyl)pyridine-2,6-diyl)bis(5,10-dihydrobenzo[b][1,5]naphthyridine)), has been successfully synthesized by mixing an NAD+-type ligand, bbnp (bbnp = 2,2′-(4-(tert-butyl)pyridine-2,6-diyl)bis(benzo[b][1,5]naphthyridine)), and [Ru(CO)2Cl2] under moderate water-gas-shift reaction conditions, which has been fully characterized by single-crystal X-ray structure analysis, ESI-TOF mass spectrometry, and NMR spectroscopy.
AB - A four-electron-reduced ruthenium(ii) NADH-type complex, [Ru(bbnpH4)(CO)2Cl](PF6) (bbnpH4 = 2,2′-(4-(tert-butyl)pyridine-2,6-diyl)bis(5,10-dihydrobenzo[b][1,5]naphthyridine)), has been successfully synthesized by mixing an NAD+-type ligand, bbnp (bbnp = 2,2′-(4-(tert-butyl)pyridine-2,6-diyl)bis(benzo[b][1,5]naphthyridine)), and [Ru(CO)2Cl2] under moderate water-gas-shift reaction conditions, which has been fully characterized by single-crystal X-ray structure analysis, ESI-TOF mass spectrometry, and NMR spectroscopy.
UR - http://www.scopus.com/inward/record.url?scp=84994275448&partnerID=8YFLogxK
U2 - 10.1039/c6dt02759h
DO - 10.1039/c6dt02759h
M3 - 学術論文
AN - SCOPUS:84994275448
SN - 1477-9226
VL - 45
SP - 16130
EP - 16133
JO - Dalton Transactions
JF - Dalton Transactions
IS - 41
ER -