Mild deuteration method of terminal alkynes in heavy water using reusable basic resin

Tsuyoshi Yamada; Kwihwan Park; Yasunari Monguchi; Yoshinari Sawama; Hironao Sajiki

doi:10.1039/c5ra18921g

Mild deuteration method of terminal alkynes in heavy water using reusable basic resin

Tsuyoshi Yamada, Kwihwan Park, Yasunari Monguchi, Yoshinari Sawama^*, Hironao Sajiki

^*この論文の責任著者

薬品製造学研究室

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

21 被引用数 (Scopus)

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The mild and efficient deuteration of terminal alkynes (mono-substituted alkynes) proceeded in the presence of a basic anion exchange resin, WA30, which is a polystyrene polymer bearing a tertiary amine residue on the aromatic nuclei, in heavy water (D₂O) at room temperature. WA30 could be easily removed by a simple filtration and repeatedly reused.

本文言語	英語
ページ（範囲）	92954-92957
ページ数	4
ジャーナル	RSC Advances
巻	5
号	113
DOI	https://doi.org/10.1039/c5ra18921g
出版ステータス	出版済み - 2015

ASJC Scopus 主題領域

化学一般
化学工学一般

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10.1039/c5ra18921g

引用スタイル

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abstract = "The mild and efficient deuteration of terminal alkynes (mono-substituted alkynes) proceeded in the presence of a basic anion exchange resin, WA30, which is a polystyrene polymer bearing a tertiary amine residue on the aromatic nuclei, in heavy water (D2O) at room temperature. WA30 could be easily removed by a simple filtration and repeatedly reused.",

author = "Tsuyoshi Yamada and Kwihwan Park and Yasunari Monguchi and Yoshinari Sawama and Hironao Sajiki",

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AU - Sajiki, Hironao

PY - 2015

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AB - The mild and efficient deuteration of terminal alkynes (mono-substituted alkynes) proceeded in the presence of a basic anion exchange resin, WA30, which is a polystyrene polymer bearing a tertiary amine residue on the aromatic nuclei, in heavy water (D2O) at room temperature. WA30 could be easily removed by a simple filtration and repeatedly reused.

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Mild deuteration method of terminal alkynes in heavy water using reusable basic resin

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