Luminescent copper(I) complexes with halogenido-bridged dimeric core

Kiyoshi Tsuge; Yuko Chishina; Hanako Hashiguchi; Yoichi Sasaki; Masako Kato; Shoji Ishizaka; Noboru Kitamura

doi:10.1016/j.ccr.2015.03.022

Luminescent copper(I) complexes with halogenido-bridged dimeric core

Kiyoshi Tsuge^*, Yuko Chishina, Hanako Hashiguchi, Yoichi Sasaki, Masako Kato, Shoji Ishizaka, Noboru Kitamura

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 総説 › 査読

240 被引用数 (Scopus)

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Neutral halogenido copper(I) units {Cu_nX_n} are widely found in the luminescent copper(I) complexes. In this review, we describe the luminescent properties of complexes with the halogenido-bridged dimeric core, {Cu₂(μ-X)₂}, which is one of the basic structural motifs of {Cu_nX_n}, as well as their synthetic methods and structural features. The available emissive excited states and their approximate energies are discussed by comparing the emission energies among the complexes with different ligand combinations. The trend of the quantum yields in the {Cu₂X₂} complexes will also be discussed.

本文言語	英語
ページ（範囲）	636-651
ページ数	16
ジャーナル	Coordination Chemistry Reviews
巻	306
DOI	https://doi.org/10.1016/j.ccr.2015.03.022
出版ステータス	出版済み - 2016/01/01

ASJC Scopus 主題領域

化学一般
材料化学
無機化学
物理化学および理論化学

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10.1016/j.ccr.2015.03.022

引用スタイル

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title = "Luminescent copper(I) complexes with halogenido-bridged dimeric core",

abstract = "Neutral halogenido copper(I) units {CunXn} are widely found in the luminescent copper(I) complexes. In this review, we describe the luminescent properties of complexes with the halogenido-bridged dimeric core, {Cu2(μ-X)2}, which is one of the basic structural motifs of {CunXn}, as well as their synthetic methods and structural features. The available emissive excited states and their approximate energies are discussed by comparing the emission energies among the complexes with different ligand combinations. The trend of the quantum yields in the {Cu2X2} complexes will also be discussed.",

keywords = "Copper, Dimeric core, Emission color, Halogenido-Bridge, Luminescence, Quantum yield",

author = "Kiyoshi Tsuge and Yuko Chishina and Hanako Hashiguchi and Yoichi Sasaki and Masako Kato and Shoji Ishizaka and Noboru Kitamura",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2016",

month = jan,

day = "1",

doi = "10.1016/j.ccr.2015.03.022",

language = "英語",

volume = "306",

pages = "636--651",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

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TY - JOUR

T1 - Luminescent copper(I) complexes with halogenido-bridged dimeric core

AU - Tsuge, Kiyoshi

AU - Chishina, Yuko

AU - Hashiguchi, Hanako

AU - Sasaki, Yoichi

AU - Kato, Masako

AU - Ishizaka, Shoji

AU - Kitamura, Noboru

PY - 2016/1/1

Y1 - 2016/1/1

N2 - Neutral halogenido copper(I) units {CunXn} are widely found in the luminescent copper(I) complexes. In this review, we describe the luminescent properties of complexes with the halogenido-bridged dimeric core, {Cu2(μ-X)2}, which is one of the basic structural motifs of {CunXn}, as well as their synthetic methods and structural features. The available emissive excited states and their approximate energies are discussed by comparing the emission energies among the complexes with different ligand combinations. The trend of the quantum yields in the {Cu2X2} complexes will also be discussed.

AB - Neutral halogenido copper(I) units {CunXn} are widely found in the luminescent copper(I) complexes. In this review, we describe the luminescent properties of complexes with the halogenido-bridged dimeric core, {Cu2(μ-X)2}, which is one of the basic structural motifs of {CunXn}, as well as their synthetic methods and structural features. The available emissive excited states and their approximate energies are discussed by comparing the emission energies among the complexes with different ligand combinations. The trend of the quantum yields in the {Cu2X2} complexes will also be discussed.

KW - Copper

KW - Dimeric core

KW - Emission color

KW - Halogenido-Bridge

KW - Luminescence

KW - Quantum yield

UR - http://www.scopus.com/inward/record.url?scp=84949317521&partnerID=8YFLogxK

U2 - 10.1016/j.ccr.2015.03.022

DO - 10.1016/j.ccr.2015.03.022

M3 - 総説

AN - SCOPUS:84949317521

SN - 0010-8545

VL - 306

SP - 636

EP - 651

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

ER -

Luminescent copper(I) complexes with halogenido-bridged dimeric core

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