Luminescent copper(I) complexes with halogenido-bridged dimeric core

Kiyoshi Tsuge; Yuko Chishina; Hanako Hashiguchi; Yoichi Sasaki; Masako Kato; Shoji Ishizaka; Noboru Kitamura

doi:10.1016/j.ccr.2015.03.022

Luminescent copper(I) complexes with halogenido-bridged dimeric core

Kiyoshi Tsuge^*, Yuko Chishina, Hanako Hashiguchi, Yoichi Sasaki, Masako Kato, Shoji Ishizaka, Noboru Kitamura

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Review article › peer-review

240 Scopus citations

Abstract

Neutral halogenido copper(I) units {Cu_nX_n} are widely found in the luminescent copper(I) complexes. In this review, we describe the luminescent properties of complexes with the halogenido-bridged dimeric core, {Cu₂(μ-X)₂}, which is one of the basic structural motifs of {Cu_nX_n}, as well as their synthetic methods and structural features. The available emissive excited states and their approximate energies are discussed by comparing the emission energies among the complexes with different ligand combinations. The trend of the quantum yields in the {Cu₂X₂} complexes will also be discussed.

Original language	English
Pages (from-to)	636-651
Number of pages	16
Journal	Coordination Chemistry Reviews
Volume	306
DOIs	https://doi.org/10.1016/j.ccr.2015.03.022
State	Published - 2016/01/01

Keywords

Copper
Dimeric core
Emission color
Halogenido-Bridge
Luminescence
Quantum yield

ASJC Scopus subject areas

General Chemistry
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1016/j.ccr.2015.03.022

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title = "Luminescent copper(I) complexes with halogenido-bridged dimeric core",

abstract = "Neutral halogenido copper(I) units {CunXn} are widely found in the luminescent copper(I) complexes. In this review, we describe the luminescent properties of complexes with the halogenido-bridged dimeric core, {Cu2(μ-X)2}, which is one of the basic structural motifs of {CunXn}, as well as their synthetic methods and structural features. The available emissive excited states and their approximate energies are discussed by comparing the emission energies among the complexes with different ligand combinations. The trend of the quantum yields in the {Cu2X2} complexes will also be discussed.",

keywords = "Copper, Dimeric core, Emission color, Halogenido-Bridge, Luminescence, Quantum yield",

author = "Kiyoshi Tsuge and Yuko Chishina and Hanako Hashiguchi and Yoichi Sasaki and Masako Kato and Shoji Ishizaka and Noboru Kitamura",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2016",

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day = "1",

doi = "10.1016/j.ccr.2015.03.022",

language = "英語",

volume = "306",

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journal = "Coordination Chemistry Reviews",

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TY - JOUR

T1 - Luminescent copper(I) complexes with halogenido-bridged dimeric core

AU - Tsuge, Kiyoshi

AU - Chishina, Yuko

AU - Hashiguchi, Hanako

AU - Sasaki, Yoichi

AU - Kato, Masako

AU - Ishizaka, Shoji

AU - Kitamura, Noboru

PY - 2016/1/1

Y1 - 2016/1/1

N2 - Neutral halogenido copper(I) units {CunXn} are widely found in the luminescent copper(I) complexes. In this review, we describe the luminescent properties of complexes with the halogenido-bridged dimeric core, {Cu2(μ-X)2}, which is one of the basic structural motifs of {CunXn}, as well as their synthetic methods and structural features. The available emissive excited states and their approximate energies are discussed by comparing the emission energies among the complexes with different ligand combinations. The trend of the quantum yields in the {Cu2X2} complexes will also be discussed.

AB - Neutral halogenido copper(I) units {CunXn} are widely found in the luminescent copper(I) complexes. In this review, we describe the luminescent properties of complexes with the halogenido-bridged dimeric core, {Cu2(μ-X)2}, which is one of the basic structural motifs of {CunXn}, as well as their synthetic methods and structural features. The available emissive excited states and their approximate energies are discussed by comparing the emission energies among the complexes with different ligand combinations. The trend of the quantum yields in the {Cu2X2} complexes will also be discussed.

KW - Copper

KW - Dimeric core

KW - Emission color

KW - Halogenido-Bridge

KW - Luminescence

KW - Quantum yield

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U2 - 10.1016/j.ccr.2015.03.022

DO - 10.1016/j.ccr.2015.03.022

M3 - 総説

AN - SCOPUS:84949317521

SN - 0010-8545

VL - 306

SP - 636

EP - 651

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

ER -

Luminescent copper(I) complexes with halogenido-bridged dimeric core

Abstract

Keywords

ASJC Scopus subject areas

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