抄録
New polypyridine-macrocyclic receptors for glucopyranosides were designed and synthesized. The artificial receptors possess a terpyridine skeleton as a hydrogen-bonding site and a flexible polyoxyethylene chain as a bridge for the macrocyclic structure, in which the cavity of the receptors is large enough to incorporate pyranosides. The receptors showed high affinities for n-octyl β-(D)-glucopyranoside, and selective binding of the receptors was observed between epimeric pyranosides. The results obtained in this paper demonstrated versatility of the terpyridine skeleton as a hydrogenbonding site for saccharides.
本文言語 | 英語 |
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ページ(範囲) | 8170-8176 |
ページ数 | 7 |
ジャーナル | Journal of Organic Chemistry |
巻 | 64 |
号 | 22 |
DOI | |
出版ステータス | 出版済み - 1999/10/29 |
ASJC Scopus 主題領域
- 有機化学