Glucopyranoside recognition by polypyridine-macrocyclic receptors possessing a wide cavity with a flexible linkage

Masahiko Inouye*, Junya Chiba, Hiroyuki Nakazumi

*この論文の責任著者

研究成果: ジャーナルへの寄稿学術論文査読

50 被引用数 (Scopus)

抄録

New polypyridine-macrocyclic receptors for glucopyranosides were designed and synthesized. The artificial receptors possess a terpyridine skeleton as a hydrogen-bonding site and a flexible polyoxyethylene chain as a bridge for the macrocyclic structure, in which the cavity of the receptors is large enough to incorporate pyranosides. The receptors showed high affinities for n-octyl β-(D)-glucopyranoside, and selective binding of the receptors was observed between epimeric pyranosides. The results obtained in this paper demonstrated versatility of the terpyridine skeleton as a hydrogenbonding site for saccharides.

本文言語英語
ページ(範囲)8170-8176
ページ数7
ジャーナルJournal of Organic Chemistry
64
22
DOI
出版ステータス出版済み - 1999/10/29

ASJC Scopus 主題領域

  • 有機化学

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