Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion

Mitsunori Oda; Takanori Kajioka; Tetsuo Okujima; Shunji Itoh; Noboru Morita; Ryuta Miyatake; Shigeyasu Kuroda

doi:10.1246/cl.1997.1011

Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion

Mitsunori Oda^*, Takanori Kajioka, Tetsuo Okujima, Shunji Itoh, Noboru Morita, Ryuta Miyatake, Shigeyasu Kuroda

^*この論文の責任著者

環境安全推進センター

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

9 被引用数 (Scopus)

抄録

The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at - 20°C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.

本文言語	英語
ページ（範囲）	1011-1012
ページ数	2
ジャーナル	Chemistry Letters
号	10
DOI	https://doi.org/10.1246/cl.1997.1011
出版ステータス	出版済み - 1997

ASJC Scopus 主題領域

化学一般

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10.1246/cl.1997.1011

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title = "Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion",

abstract = "The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at - 20°C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.",

author = "Mitsunori Oda and Takanori Kajioka and Tetsuo Okujima and Shunji Itoh and Noboru Morita and Ryuta Miyatake and Shigeyasu Kuroda",

year = "1997",

doi = "10.1246/cl.1997.1011",

language = "英語",

pages = "1011--1012",

journal = "Chemistry Letters",

issn = "0366-7022",

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TY - JOUR

T1 - Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion

AU - Oda, Mitsunori

AU - Kajioka, Takanori

AU - Okujima, Tetsuo

AU - Itoh, Shunji

AU - Morita, Noboru

AU - Miyatake, Ryuta

AU - Kuroda, Shigeyasu

PY - 1997

Y1 - 1997

N2 - The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at - 20°C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.

AB - The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at - 20°C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.

UR - http://www.scopus.com/inward/record.url?scp=21944454913&partnerID=8YFLogxK

U2 - 10.1246/cl.1997.1011

DO - 10.1246/cl.1997.1011

M3 - 学術論文

AN - SCOPUS:21944454913

SN - 0366-7022

SP - 1011

EP - 1012

JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion

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