Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion

Mitsunori Oda; Takanori Kajioka; Tetsuo Okujima; Shunji Itoh; Noboru Morita; Ryuta Miyatake; Shigeyasu Kuroda

doi:10.1246/cl.1997.1011

Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion

Mitsunori Oda^*, Takanori Kajioka, Tetsuo Okujima, Shunji Itoh, Noboru Morita, Ryuta Miyatake, Shigeyasu Kuroda

^*Corresponding author for this work

Center for Environmental Conservation and Research Safety

Research output: Contribution to journal › Article › peer-review

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Abstract

The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at - 20°C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.

Original language	English
Pages (from-to)	1011-1012
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.1997.1011
State	Published - 1997

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.1997.1011

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title = "Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion",

abstract = "The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at - 20°C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.",

author = "Mitsunori Oda and Takanori Kajioka and Tetsuo Okujima and Shunji Itoh and Noboru Morita and Ryuta Miyatake and Shigeyasu Kuroda",

year = "1997",

doi = "10.1246/cl.1997.1011",

language = "英語",

pages = "1011--1012",

journal = "Chemistry Letters",

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TY - JOUR

T1 - Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion

AU - Oda, Mitsunori

AU - Kajioka, Takanori

AU - Okujima, Tetsuo

AU - Itoh, Shunji

AU - Morita, Noboru

AU - Miyatake, Ryuta

AU - Kuroda, Shigeyasu

PY - 1997

Y1 - 1997

N2 - The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at - 20°C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.

AB - The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at - 20°C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.

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U2 - 10.1246/cl.1997.1011

DO - 10.1246/cl.1997.1011

M3 - 学術論文

AN - SCOPUS:21944454913

SN - 0366-7022

SP - 1011

EP - 1012

JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Generation, characterization and some reactions of 1,1-ethylene-1H-azulenium ion

Abstract

ASJC Scopus subject areas

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