Diastereo- and enantioselective intramolecular 1,6-C-H insertion reactions of α-diazo esters catalyzed by chiral dirhodium(II) carboxylates

Keyphrases

• Enantioselectivity 100%
• Dirhodium Complex 100%
• Carboxylate 100%
• Diastereoselective 100%
• C-H Insertion Reaction 100%
• Diazoester 100%
• Tetrakis 50%
• Tert 50%
• Diastereoselectivity 50%
• Chemoselective 50%
• C-H Insertion 50%
• Rh2(S-PTTL)4 50%
• Phthaloyl Dichloride 50%
• Catalytic Asymmetric 50%

Chemistry

• Insertion Reaction 100%
• Carboxylic Acid 100%
• Chemoselectivity 50%
• Diastereoselectivity 50%
• Leucinate 50%