@article{2069b091abd74ffea85663e33510c068,
title = "Diastereo- and enantioselective intramolecular 1,6-C-H insertion reactions of α-diazo esters catalyzed by chiral dirhodium(II) carboxylates",
abstract = "The first catalytic asymmetric intramolecular 1,6-C-H insertion reaction of α-diazo esters is described. With dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate], Rh2(S-PTTL)4, the C-H insertion proceeded in a chemoselective manner to give 2-alkenyltetrahydropyran-3-carboxylates with up to 95% ee and perfect cis diastereoselectivity.",
keywords = "Asymmetric catalysis, C-H insertion, Dirhodium(II) complex, Six-membered heterocycle, α-Diazo ester",
author = "Motoki Ito and Yuji Kondo and Hisanori Nambu and Masahiro Anada and Koji Takeda and Shunichi Hashimoto",
note = "Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd. All rights reserved.",
year = "2015",
month = mar,
day = "11",
doi = "10.1016/j.tetlet.2015.01.125",
language = "英語",
volume = "56",
pages = "1397--1400",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Ltd.",
number = "11",
}