Application of palladium(II) complex with bidentate phosphine sulfide ligands to palladium-catalyzed C-C coupling reaction

Sen ichi Aizawa*, Mayumi Kondo, Ryuta Miyatake, Mitsuyoshi Tamai

*この論文の責任著者

研究成果: ジャーナルへの寄稿学術論文査読

17 被引用数 (Scopus)

抄録

A phosphine sulfide Pd(II) complex, [Pd(p2S2)2](BF4)2 (1) (p2S2 = 1,2-bis(diphenylphosphino)ethane disulfide), was synthesized and characterized by an X-ray crystal structure analysis and 31P NMR spectroscopy. The p2S2 ligand exchange rate of 1 with free p2S2 in chloroform was revealed to be comparable to the general solvent exchange rate on Pd(II). The catalytic activity of 1 was evaluated by carrying out the Heck reaction. The diminishing of the induction period and acceleration of the reaction were observed for 1 by comparing the phosphine Pd(II) complexes with a leaving chloro ligand, [PdCl(p3)]Cl (p3 = bis[2-(diphenylphosphino)ethyl]phenylphosphine) and [PdCl(pp3)]Cl (pp3 = tris[2-(diphenylphosphino)ethyl]phosphine), and the catalytic activity was comparable to that of the phosphine Pd(0) complex, [Pd(PPh3)4]. Such a high catalytic activity of 1 is attributed to the π-accepting ability of the phosphine sulfide S atom which stabilizes the catalytically active Pd(0) species electronically and weak σ-donation of the S atom which does not block the formation and a subsequent reaction of the Pd(II) substrate adduct in the catalytic cycle.

本文言語英語
ページ(範囲)2809-2813
ページ数5
ジャーナルInorganica Chimica Acta
360
8
DOI
出版ステータス出版済み - 2007/05/30

ASJC Scopus 主題領域

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

フィンガープリント

「Application of palladium(II) complex with bidentate phosphine sulfide ligands to palladium-catalyzed C-C coupling reaction」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル