The reaction of diazines with allyltributyltin via N-alkoxycarbonyldiazinium salts

Takashi Itoh; Hiroshi Hasegawa; Kazuhiro Nagata; Yûji Matsuya; Akio Ohsawa

doi:10.3987/com-93-s92

The reaction of diazines with allyltributyltin via N-alkoxycarbonyldiazinium salts

Takashi Itoh^*, Hiroshi Hasegawa, Kazuhiro Nagata, Yûji Matsuya, Akio Ohsawa

^*Corresponding author for this work

Synthetic and Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Pyridazines were allowed to react with allyltributyltin in the presence of chloroformate to give 1-alkoxycarbonyl-6-allyl- and 1-alkoxycarbonyl-4-allyldihydro-pyridazines as major and minor products, respectively. The reaction was applied to other diazines, and tetrahydro-adducts were obtained in the case of pyrimidine and pyrazine. Benzo-fused diazines also reacted in the same manner to afford the allyl-adducts in good yields.

Original language	English
Pages (from-to)	709-713
Number of pages	5
Journal	Heterocycles
Volume	37
Issue number	2
DOIs	https://doi.org/10.3987/com-93-s92
State	Published - 1994/03/03

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

Access to Document

10.3987/com-93-s92

Cite this

@article{ab06eaa8734a4595aa0384545c2a76d3,

title = "The reaction of diazines with allyltributyltin via N-alkoxycarbonyldiazinium salts",

abstract = "Pyridazines were allowed to react with allyltributyltin in the presence of chloroformate to give 1-alkoxycarbonyl-6-allyl- and 1-alkoxycarbonyl-4-allyldihydro-pyridazines as major and minor products, respectively. The reaction was applied to other diazines, and tetrahydro-adducts were obtained in the case of pyrimidine and pyrazine. Benzo-fused diazines also reacted in the same manner to afford the allyl-adducts in good yields.",

author = "Takashi Itoh and Hiroshi Hasegawa and Kazuhiro Nagata and Y{\^u}ji Matsuya and Akio Ohsawa",

year = "1994",

month = mar,

day = "3",

doi = "10.3987/com-93-s92",

language = "英語",

volume = "37",

pages = "709--713",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

number = "2",

}

TY - JOUR

T1 - The reaction of diazines with allyltributyltin via N-alkoxycarbonyldiazinium salts

AU - Itoh, Takashi

AU - Hasegawa, Hiroshi

AU - Nagata, Kazuhiro

AU - Matsuya, Yûji

AU - Ohsawa, Akio

PY - 1994/3/3

Y1 - 1994/3/3

N2 - Pyridazines were allowed to react with allyltributyltin in the presence of chloroformate to give 1-alkoxycarbonyl-6-allyl- and 1-alkoxycarbonyl-4-allyldihydro-pyridazines as major and minor products, respectively. The reaction was applied to other diazines, and tetrahydro-adducts were obtained in the case of pyrimidine and pyrazine. Benzo-fused diazines also reacted in the same manner to afford the allyl-adducts in good yields.

AB - Pyridazines were allowed to react with allyltributyltin in the presence of chloroformate to give 1-alkoxycarbonyl-6-allyl- and 1-alkoxycarbonyl-4-allyldihydro-pyridazines as major and minor products, respectively. The reaction was applied to other diazines, and tetrahydro-adducts were obtained in the case of pyrimidine and pyrazine. Benzo-fused diazines also reacted in the same manner to afford the allyl-adducts in good yields.

UR - http://www.scopus.com/inward/record.url?scp=0008581968&partnerID=8YFLogxK

U2 - 10.3987/com-93-s92

DO - 10.3987/com-93-s92

M3 - 学術論文

AN - SCOPUS:0008581968

SN - 0385-5414

VL - 37

SP - 709

EP - 713

JO - Heterocycles

JF - Heterocycles

IS - 2

ER -

The reaction of diazines with allyltributyltin via N-alkoxycarbonyldiazinium salts

Abstract

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this