Synthesis and properties of anti-6,15-epithia-8,13-methanobenzo[e] [14]annulene-7,14-dione, anti-5,14-epithia-7,12-methanofuro[3,4-e]-[14]annulene-5,13-diones, and their ionic species

Shengli Zuo, Shigeyasu Kuroda*, Mitsunori Oda, Shin Ya Kuramoto, Yoshihiro Mizukami, Atsushi Fukuta, Yukiyasu Hirano, Teruhiko Nishikawa, Shinji Furuta, Ryuta Miyatake, Sha I. Shaheen, Takanori Kajioka, Mayumi Kyogoku

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The sulfur bridged annulene diones fused with benzene and furan were synthesized, and their 1H and 13C NMR spectra in strong acid media indicated formation of dicationic species in which the positive charges localized on the carbonyl carbons, mainly due to the unfavorable p-orbital overlap.

Original languageEnglish
Pages (from-to)159-170
Number of pages12
JournalHeterocycles
Volume54
Issue number1
DOIs
StatePublished - 2001/01/01

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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