Quantum precession of HCl molecule in hydroquinone clathrate

S. Takeda; H. Kataoka; K. Shibata; S. Ikeda; T. Matsuo; C. J. Carlile

doi:10.1016/0921-4526(94)90311-5

Quantum precession of HCl molecule in hydroquinone clathrate

S. Takeda^*, H. Kataoka, K. Shibata, S. Ikeda, T. Matsuo, C. J. Carlile

^*Corresponding author for this work

Joint Institute of Teacher Education

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The dynamical behaviour of HCl in the cage of β-hydroquinone clathrate was investigated by neutron scattering with particular reference to the phase transition at 12.3 K. A quantum precessional transition of HCl was observed at 4.3 meV as a broad peak, below the phase transition temperature for the stoichiometric compound. The peak width became much broader for the non-stoichiometric clathrate in which a fraction of cages are unoccupied. The peak disappeared for the deuterated compound. Quasielastic scattering appeared above the phase transition temperature (12.3 K).

Original language	English
Pages (from-to)	315-319
Number of pages	5
Journal	Physica B: Condensed Matter
Volume	202
Issue number	3-4
DOIs	https://doi.org/10.1016/0921-4526(94)90311-5
State	Published - 1994/10

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering

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@article{117ae47d7ea840058ea4a79a1db221cc,

title = "Quantum precession of HCl molecule in hydroquinone clathrate",

abstract = "The dynamical behaviour of HCl in the cage of β-hydroquinone clathrate was investigated by neutron scattering with particular reference to the phase transition at 12.3 K. A quantum precessional transition of HCl was observed at 4.3 meV as a broad peak, below the phase transition temperature for the stoichiometric compound. The peak width became much broader for the non-stoichiometric clathrate in which a fraction of cages are unoccupied. The peak disappeared for the deuterated compound. Quasielastic scattering appeared above the phase transition temperature (12.3 K).",

author = "S. Takeda and H. Kataoka and K. Shibata and S. Ikeda and T. Matsuo and Carlile, {C. J.}",

year = "1994",

month = oct,

doi = "10.1016/0921-4526(94)90311-5",

language = "英語",

volume = "202",

pages = "315--319",

journal = "Physica B: Condensed Matter",

issn = "0921-4526",

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T1 - Quantum precession of HCl molecule in hydroquinone clathrate

AU - Takeda, S.

AU - Kataoka, H.

AU - Shibata, K.

AU - Ikeda, S.

AU - Matsuo, T.

AU - Carlile, C. J.

PY - 1994/10

Y1 - 1994/10

N2 - The dynamical behaviour of HCl in the cage of β-hydroquinone clathrate was investigated by neutron scattering with particular reference to the phase transition at 12.3 K. A quantum precessional transition of HCl was observed at 4.3 meV as a broad peak, below the phase transition temperature for the stoichiometric compound. The peak width became much broader for the non-stoichiometric clathrate in which a fraction of cages are unoccupied. The peak disappeared for the deuterated compound. Quasielastic scattering appeared above the phase transition temperature (12.3 K).

AB - The dynamical behaviour of HCl in the cage of β-hydroquinone clathrate was investigated by neutron scattering with particular reference to the phase transition at 12.3 K. A quantum precessional transition of HCl was observed at 4.3 meV as a broad peak, below the phase transition temperature for the stoichiometric compound. The peak width became much broader for the non-stoichiometric clathrate in which a fraction of cages are unoccupied. The peak disappeared for the deuterated compound. Quasielastic scattering appeared above the phase transition temperature (12.3 K).

UR - http://www.scopus.com/inward/record.url?scp=9444263609&partnerID=8YFLogxK

U2 - 10.1016/0921-4526(94)90311-5

DO - 10.1016/0921-4526(94)90311-5

M3 - 学術論文

AN - SCOPUS:9444263609

SN - 0921-4526

VL - 202

SP - 315

EP - 319

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter

IS - 3-4

ER -

Quantum precession of HCl molecule in hydroquinone clathrate

Abstract

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