Impacts of framework Al distribution and acidic properties of Cu-exchanged CHA-type zeolite on catalytic conversion of methane into methanol followed by lower hydrocarbons

Kengo Nakamura; Peipei Xiao; Ryota Osuga; Yong Wang; Shuhei Yasuda; Takeshi Matsumoto; Junko N. Kondo; Mizuho Yabushita; Atsushi Muramatsu; Hermann Gies; Toshiyuki Yokoi

doi:10.1039/d3cy00127j

Impacts of framework Al distribution and acidic properties of Cu-exchanged CHA-type zeolite on catalytic conversion of methane into methanol followed by lower hydrocarbons

Kengo Nakamura, Peipei Xiao, Ryota Osuga, Yong Wang, Shuhei Yasuda, Takeshi Matsumoto, Junko N. Kondo, Mizuho Yabushita, Atsushi Muramatsu, Hermann Gies, Toshiyuki Yokoi^*

^*Corresponding author for this work

Applied Chemistry

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13 Scopus citations

Abstract

This work highlighted the significance of the Al distribution in the CHA-type zeolite in the formation of active Cu species for oxidative conversion of CH₄; isolated Al atoms in the zeolite framework are found to be advantageous for producing CH₃OH. The acid sites also played an important role in the production of hydrocarbons; produced CH₃OH is converted into hydrocarbons over the acid sites.

Original language	English
Pages (from-to)	2648-2651
Number of pages	4
Journal	Catalysis Science and Technology
Volume	13
Issue number	9
DOIs	https://doi.org/10.1039/d3cy00127j
State	Published - 2023/03/14

ASJC Scopus subject areas

Catalysis

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10.1039/d3cy00127j

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Nakamura, K., Xiao, P., Osuga, R., Wang, Y., Yasuda, S., Matsumoto, T., Kondo, J. N., Yabushita, M., Muramatsu, A., Gies, H., & Yokoi, T. (2023). Impacts of framework Al distribution and acidic properties of Cu-exchanged CHA-type zeolite on catalytic conversion of methane into methanol followed by lower hydrocarbons. Catalysis Science and Technology, 13(9), 2648-2651. https://doi.org/10.1039/d3cy00127j

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title = "Impacts of framework Al distribution and acidic properties of Cu-exchanged CHA-type zeolite on catalytic conversion of methane into methanol followed by lower hydrocarbons",

abstract = "This work highlighted the significance of the Al distribution in the CHA-type zeolite in the formation of active Cu species for oxidative conversion of CH4; isolated Al atoms in the zeolite framework are found to be advantageous for producing CH3OH. The acid sites also played an important role in the production of hydrocarbons; produced CH3OH is converted into hydrocarbons over the acid sites.",

author = "Kengo Nakamura and Peipei Xiao and Ryota Osuga and Yong Wang and Shuhei Yasuda and Takeshi Matsumoto and Kondo, {Junko N.} and Mizuho Yabushita and Atsushi Muramatsu and Hermann Gies and Toshiyuki Yokoi",

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year = "2023",

month = mar,

day = "14",

doi = "10.1039/d3cy00127j",

language = "英語",

volume = "13",

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Nakamura, K, Xiao, P, Osuga, R, Wang, Y, Yasuda, S, Matsumoto, T, Kondo, JN, Yabushita, M, Muramatsu, A, Gies, H & Yokoi, T 2023, 'Impacts of framework Al distribution and acidic properties of Cu-exchanged CHA-type zeolite on catalytic conversion of methane into methanol followed by lower hydrocarbons', Catalysis Science and Technology, vol. 13, no. 9, pp. 2648-2651. https://doi.org/10.1039/d3cy00127j

Impacts of framework Al distribution and acidic properties of Cu-exchanged CHA-type zeolite on catalytic conversion of methane into methanol followed by lower hydrocarbons. / Nakamura, Kengo; Xiao, Peipei; Osuga, Ryota et al.
In: Catalysis Science and Technology, Vol. 13, No. 9, 14.03.2023, p. 2648-2651.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Impacts of framework Al distribution and acidic properties of Cu-exchanged CHA-type zeolite on catalytic conversion of methane into methanol followed by lower hydrocarbons

AU - Nakamura, Kengo

AU - Xiao, Peipei

AU - Osuga, Ryota

AU - Wang, Yong

AU - Yasuda, Shuhei

AU - Matsumoto, Takeshi

AU - Kondo, Junko N.

AU - Yabushita, Mizuho

AU - Muramatsu, Atsushi

AU - Gies, Hermann

AU - Yokoi, Toshiyuki

PY - 2023/3/14

Y1 - 2023/3/14

N2 - This work highlighted the significance of the Al distribution in the CHA-type zeolite in the formation of active Cu species for oxidative conversion of CH4; isolated Al atoms in the zeolite framework are found to be advantageous for producing CH3OH. The acid sites also played an important role in the production of hydrocarbons; produced CH3OH is converted into hydrocarbons over the acid sites.

AB - This work highlighted the significance of the Al distribution in the CHA-type zeolite in the formation of active Cu species for oxidative conversion of CH4; isolated Al atoms in the zeolite framework are found to be advantageous for producing CH3OH. The acid sites also played an important role in the production of hydrocarbons; produced CH3OH is converted into hydrocarbons over the acid sites.

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U2 - 10.1039/d3cy00127j

DO - 10.1039/d3cy00127j

M3 - 学術論文

AN - SCOPUS:85159399939

SN - 2044-4753

VL - 13

SP - 2648

EP - 2651

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 9

ER -

Impacts of framework Al distribution and acidic properties of Cu-exchanged CHA-type zeolite on catalytic conversion of methane into methanol followed by lower hydrocarbons

Abstract

ASJC Scopus subject areas

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