Research output per year
Research output per year
Project Details
Abstract
Thermal deactivation pathways of phosphorescent state in d6 and d8metal complexes were elucidated based on the pathways calculated using DFT and observed activation energies and volumes. It was revealed that the rate-determining step of the deactivation process was at dd->GS for Ru（II) tris-bipyridine complexes whereas it was located between MLCT and dd for Pt（II) acac complexes.
| Status | Finished |
|---|---|
| Effective start/end date | 2010/01/01 → 2012/12/31 |
Funding
- Japan Society for the Promotion of Science: ¥5,070,000.00
Keywords
- リン光
- 遷移金属錯体
- 熱失活
- dd状態
- 反応機構
- 活性化体積
- 無輻射失活
- ルテニウム錯体
- MLCT
Research output
- 3 Article
-
Photoinduced electron transfer of platinum(ii) bipyridine diacetylides linked by triphenylamine- and naphthaleneimide-derivatives and their application to photoelectric conversion systems
Suzuki, S., Matsumoto, Y., Tsubamoto, M., Sugimura, R., Kozaki, M., Kimoto, K., Iwamura, M., Nozaki, K., Senju, N., Uragami, C., Hashimoto, H., Muramatsu, Y., Konno, A. & Okada, K., 2013/06/07, In: Physical Chemistry Chemical Physics. 15, 21, p. 8088-8094 7 p.Research output: Contribution to journal › Article › peer-review
46 Scopus citations -
Real-time observation of tight Au-Au bond formation and relevant coherent motion upon photoexcitation of [Au(CN)2-] oligomers
Iwamura, M., Nozaki, K., Takeuchi, S. & Tahara, T., 2013/01/16, In: Journal of the American Chemical Society. 135, 2, p. 538-541 4 p.Research output: Contribution to journal › Article › peer-review
52 Scopus citations -
Chiral sensing using an achiral europium(III) complex by induced circularly polarized luminescence
Iwamura, M., Kimura, Y., Miyamoto, R. & Nozaki, K., 2012/04/02, In: Inorganic Chemistry. 51, 7, p. 4094-4098 5 p.Research output: Contribution to journal › Article › peer-review
63 Scopus citations