@article{fecc8bf8e884405aaf258226182f94c6,
title = "Total Synthesis of (+)-Tanikolide by a Traceless Stereoinduction Method Using Rhodium(II)-Catalyzed Oxonium Ylide Formation-[2,3]-Sigmatropic Rearrangement and NHC-Catalyzed Ring-Expansion Lactonization",
abstract = "The total synthesis of (+)-tanikolide was accomplished by a traceless stereoinduction method using the key steps of a Rh(II)-catalyzed oxonium ylide formation-[2,3]-sigmatropic rearrangement and an N-heterocyclic carbene-catalyzed ring-expansion lactonization of tetrahydrofurfural. This synthetic route is applicable to the divergent synthesis of tanikolide analogues.",
keywords = "N -heterocyclic carbine, oxonium ylides, rearrangement, rhodium, total synthesis, traceless stereoinduction",
author = "Hisanori Nambu and Hikari Jinnouchi and Tomoya Fujiwara and Takayuki Yakura",
note = "Publisher Copyright: {\textcopyright} Georg Thieme Verlag.",
year = "2016",
month = jan,
day = "26",
doi = "10.1055/s-0035-1561341",
language = "英語",
volume = "27",
pages = "1106--1109",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "7",
}