Through-Space Charge Transfer in Copper Coordination Networks with Copper-Halide Guest Anions

Hiroyoshi Ohtsu; Marie Okuyama; Takeshi Nakajima; Munetaka Iwamura; Koichi Nozaki; Daisuke Hashizume; Masaki Kawano

doi:10.1021/acs.inorgchem.1c01451

Through-Space Charge Transfer in Copper Coordination Networks with Copper-Halide Guest Anions

Hiroyoshi Ohtsu^*, Marie Okuyama, Takeshi Nakajima, Munetaka Iwamura^*, Koichi Nozaki, Daisuke Hashizume, Masaki Kawano^*

^*この論文の責任著者

理学科　化学プログラム

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

8 被引用数 (Scopus)

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We prepared coordination networks that show relatively strong emission with through-space charge-transfer (TSCT) transitions. Thermolysis of a kinetically assembled network with Cu2Br2 dimer connectors, which was assembled from a CuBr cluster and the Td ligand 4-4-tetrapyridyltetraphenylmethane (4-TPPM), generated a highly luminescent network composed of Cu+ connectors and 4-TPPM linkers with CuBr2- guests. We clarified that the electronic transitions in this network include TSCT in addition to the typical metal-ligand charge transfer (MLCT) observed in conventional Cu complexes.

本文言語	英語
ページ（範囲）	9273-9277
ページ数	5
ジャーナル	Inorganic Chemistry
巻	60
号	13
DOI	https://doi.org/10.1021/acs.inorgchem.1c01451
出版ステータス	出版済み - 2021/07/05

ASJC Scopus 主題領域

物理化学および理論化学
無機化学

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10.1021/acs.inorgchem.1c01451

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title = "Through-Space Charge Transfer in Copper Coordination Networks with Copper-Halide Guest Anions",

abstract = "We prepared coordination networks that show relatively strong emission with through-space charge-transfer (TSCT) transitions. Thermolysis of a kinetically assembled network with Cu2Br2 dimer connectors, which was assembled from a CuBr cluster and the Td ligand 4-4-tetrapyridyltetraphenylmethane (4-TPPM), generated a highly luminescent network composed of Cu+ connectors and 4-TPPM linkers with CuBr2- guests. We clarified that the electronic transitions in this network include TSCT in addition to the typical metal-ligand charge transfer (MLCT) observed in conventional Cu complexes.",

author = "Hiroyoshi Ohtsu and Marie Okuyama and Takeshi Nakajima and Munetaka Iwamura and Koichi Nozaki and Daisuke Hashizume and Masaki Kawano",

note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",

year = "2021",

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day = "5",

doi = "10.1021/acs.inorgchem.1c01451",

language = "英語",

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T1 - Through-Space Charge Transfer in Copper Coordination Networks with Copper-Halide Guest Anions

AU - Ohtsu, Hiroyoshi

AU - Okuyama, Marie

AU - Nakajima, Takeshi

AU - Iwamura, Munetaka

AU - Nozaki, Koichi

AU - Hashizume, Daisuke

AU - Kawano, Masaki

PY - 2021/7/5

Y1 - 2021/7/5

N2 - We prepared coordination networks that show relatively strong emission with through-space charge-transfer (TSCT) transitions. Thermolysis of a kinetically assembled network with Cu2Br2 dimer connectors, which was assembled from a CuBr cluster and the Td ligand 4-4-tetrapyridyltetraphenylmethane (4-TPPM), generated a highly luminescent network composed of Cu+ connectors and 4-TPPM linkers with CuBr2- guests. We clarified that the electronic transitions in this network include TSCT in addition to the typical metal-ligand charge transfer (MLCT) observed in conventional Cu complexes.

AB - We prepared coordination networks that show relatively strong emission with through-space charge-transfer (TSCT) transitions. Thermolysis of a kinetically assembled network with Cu2Br2 dimer connectors, which was assembled from a CuBr cluster and the Td ligand 4-4-tetrapyridyltetraphenylmethane (4-TPPM), generated a highly luminescent network composed of Cu+ connectors and 4-TPPM linkers with CuBr2- guests. We clarified that the electronic transitions in this network include TSCT in addition to the typical metal-ligand charge transfer (MLCT) observed in conventional Cu complexes.

UR - http://www.scopus.com/inward/record.url?scp=85110055762&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.1c01451

DO - 10.1021/acs.inorgchem.1c01451

M3 - 学術論文

C2 - 34128658

AN - SCOPUS:85110055762

SN - 0020-1669

VL - 60

SP - 9273

EP - 9277

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Through-Space Charge Transfer in Copper Coordination Networks with Copper-Halide Guest Anions

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