Thienoborepins: Conjugation characteristics in boron heterocycles

Yoshikazu Sugihara; Ryuta Miyatake; Toshiyasu Yagi; Ichiro Murata; Mamoru Jinguji; Tomoo Nakazawa; Akira Imamura

doi:10.1016/S0040-4020(01)89681-2

Thienoborepins: Conjugation characteristics in boron heterocycles

Yoshikazu Sugihara^*, Ryuta Miyatake, Toshiyasu Yagi, Ichiro Murata, Mamoru Jinguji, Tomoo Nakazawa, Akira Imamura

^*この論文の責任著者

環境安全推進センター

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

16 被引用数 (Scopus)

抄録

Protonolysis, complex-formation with amines, ab initio molecular orbital calculations with 3-21G basis set, redox potentials, and spectroscopic features of 1-phenylthieno[3,4-d]borepin (1) and 1-phenylthieno[2,3-d]borepin (2) were examined. The compound 1 was shown to be more labile than 2, which give us a guide for construction of stable heteroaromatics. Absorption and fluorescence spectra of 1 and 2 revealed the potential ability of boron heterocycles in the field of the organic optical materials.

本文言語	英語
ページ（範囲）	6495-6504
ページ数	10
ジャーナル	Tetrahedron
巻	50
号	22
DOI	https://doi.org/10.1016/S0040-4020(01)89681-2
出版ステータス	出版済み - 1994

ASJC Scopus 主題領域

生化学
創薬
有機化学

文献へのアクセス

10.1016/S0040-4020(01)89681-2

引用スタイル

@article{fadda4520e84499bac6af7aa401d8262,

title = "Thienoborepins: Conjugation characteristics in boron heterocycles",

abstract = "Protonolysis, complex-formation with amines, ab initio molecular orbital calculations with 3-21G basis set, redox potentials, and spectroscopic features of 1-phenylthieno[3,4-d]borepin (1) and 1-phenylthieno[2,3-d]borepin (2) were examined. The compound 1 was shown to be more labile than 2, which give us a guide for construction of stable heteroaromatics. Absorption and fluorescence spectra of 1 and 2 revealed the potential ability of boron heterocycles in the field of the organic optical materials.",

author = "Yoshikazu Sugihara and Ryuta Miyatake and Toshiyasu Yagi and Ichiro Murata and Mamoru Jinguji and Tomoo Nakazawa and Akira Imamura",

note = "Funding Information: AcknowledgemenWt. e appreciate the financial support of The Nishida",

year = "1994",

doi = "10.1016/S0040-4020(01)89681-2",

language = "英語",

volume = "50",

pages = "6495--6504",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Ltd.",

number = "22",

}

TY - JOUR

T1 - Thienoborepins

T2 - Conjugation characteristics in boron heterocycles

AU - Sugihara, Yoshikazu

AU - Miyatake, Ryuta

AU - Yagi, Toshiyasu

AU - Murata, Ichiro

AU - Jinguji, Mamoru

AU - Nakazawa, Tomoo

AU - Imamura, Akira

N1 - Funding Information: AcknowledgemenWt. e appreciate the financial support of The Nishida

PY - 1994

Y1 - 1994

N2 - Protonolysis, complex-formation with amines, ab initio molecular orbital calculations with 3-21G basis set, redox potentials, and spectroscopic features of 1-phenylthieno[3,4-d]borepin (1) and 1-phenylthieno[2,3-d]borepin (2) were examined. The compound 1 was shown to be more labile than 2, which give us a guide for construction of stable heteroaromatics. Absorption and fluorescence spectra of 1 and 2 revealed the potential ability of boron heterocycles in the field of the organic optical materials.

AB - Protonolysis, complex-formation with amines, ab initio molecular orbital calculations with 3-21G basis set, redox potentials, and spectroscopic features of 1-phenylthieno[3,4-d]borepin (1) and 1-phenylthieno[2,3-d]borepin (2) were examined. The compound 1 was shown to be more labile than 2, which give us a guide for construction of stable heteroaromatics. Absorption and fluorescence spectra of 1 and 2 revealed the potential ability of boron heterocycles in the field of the organic optical materials.

UR - http://www.scopus.com/inward/record.url?scp=0028355929&partnerID=8YFLogxK

U2 - 10.1016/S0040-4020(01)89681-2

DO - 10.1016/S0040-4020(01)89681-2

M3 - 学術論文

AN - SCOPUS:0028355929

SN - 0040-4020

VL - 50

SP - 6495

EP - 6504

JO - Tetrahedron

JF - Tetrahedron

IS - 22

ER -

Thienoborepins: Conjugation characteristics in boron heterocycles

抄録

ASJC Scopus 主題領域

文献へのアクセス

フィンガープリント

引用スタイル