Synthesis, Structure, and Molecular Orbital Calculation of the Bicapped Triangular Molybdenum Cluster Complex [Mo₃S₅(PMe₃)₆]

Keyphrases

• Antibonding 50%
• Bridging Ligands 50%
• Cluster Anions 50%
• Cluster Complexes 50%
• DV-Xα Method 50%
• Isoelectronic 50%
• Metal Atoms 100%
• Molecular Orbital 50%
• Molecular Orbital Calculations 100%
• Molybdenum 100%
• Molybdenum Complex 100%
• Octahedral Coordination 50%
• Rhombohedral 50%
• Structural Difference 50%
• Sulfur 100%
• T2g Orbital 50%
• Trimethylphosphine 50%
• Trinuclear Cluster 100%

Chemistry

• Lowest Unoccupied Molecular Orbital 33%
• Metal Atom 66%
• Molecular Orbital 100%
• Molybdenum 100%
• R3-C 33%
• Rhombohedral Space Group 33%
• Trimethylphosphine 33%