Synthesis, structure, and magnetic property of a dinuclear vanadium(III) complexes with N-hydroxyethyliminodiacetate

Kan Kanamori; Kyoko Ishida; Kazuya Fujimoto; Tomohiko Kuwai; Ken Ichi Okamoto

doi:10.1246/bcsj.74.2377

Synthesis, structure, and magnetic property of a dinuclear vanadium(III) complexes with N-hydroxyethyliminodiacetate

Kan Kanamori^*, Kyoko Ishida, Kazuya Fujimoto, Tomohiko Kuwai, Ken Ichi Okamoto

^*この論文の責任著者

物理学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

8 被引用数 (Scopus)

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A vanadium(III) complex with N-hydroxyethyliminodiacetate (heida(3-)) was prepared. The X-ray crystallography has revealed that the compound is a dinuclear vanadium(III) complex, which contains a di-μ-alkoxo bridge derived from the deprotonation of the hydroxyethyl group of the parent heida(2-) ligand. Each vanadium(III) center adopts a distorted octahedral structure. The temperature-dependent magnetic susceptibility measurement suggests that the electronic spin moments of the two vanadium(III) centers are antiferro-magnetically coupled (g = 1.98 and J = - 36.9 cm ^-1).

本文言語	英語
ページ（範囲）	2377-2378
ページ数	2
ジャーナル	Bulletin of the Chemical Society of Japan
巻	74
号	12
DOI	https://doi.org/10.1246/bcsj.74.2377
出版ステータス	出版済み - 2001/12

ASJC Scopus 主題領域

化学一般

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title = "Synthesis, structure, and magnetic property of a dinuclear vanadium(III) complexes with N-hydroxyethyliminodiacetate",

abstract = "A vanadium(III) complex with N-hydroxyethyliminodiacetate (heida(3-)) was prepared. The X-ray crystallography has revealed that the compound is a dinuclear vanadium(III) complex, which contains a di-μ-alkoxo bridge derived from the deprotonation of the hydroxyethyl group of the parent heida(2-) ligand. Each vanadium(III) center adopts a distorted octahedral structure. The temperature-dependent magnetic susceptibility measurement suggests that the electronic spin moments of the two vanadium(III) centers are antiferro-magnetically coupled (g = 1.98 and J = - 36.9 cm -1).",

author = "Kan Kanamori and Kyoko Ishida and Kazuya Fujimoto and Tomohiko Kuwai and Okamoto, {Ken Ichi}",

year = "2001",

month = dec,

doi = "10.1246/bcsj.74.2377",

language = "英語",

volume = "74",

pages = "2377--2378",

journal = "Bulletin of the Chemical Society of Japan",

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TY - JOUR

T1 - Synthesis, structure, and magnetic property of a dinuclear vanadium(III) complexes with N-hydroxyethyliminodiacetate

AU - Kanamori, Kan

AU - Ishida, Kyoko

AU - Fujimoto, Kazuya

AU - Kuwai, Tomohiko

AU - Okamoto, Ken Ichi

PY - 2001/12

Y1 - 2001/12

N2 - A vanadium(III) complex with N-hydroxyethyliminodiacetate (heida(3-)) was prepared. The X-ray crystallography has revealed that the compound is a dinuclear vanadium(III) complex, which contains a di-μ-alkoxo bridge derived from the deprotonation of the hydroxyethyl group of the parent heida(2-) ligand. Each vanadium(III) center adopts a distorted octahedral structure. The temperature-dependent magnetic susceptibility measurement suggests that the electronic spin moments of the two vanadium(III) centers are antiferro-magnetically coupled (g = 1.98 and J = - 36.9 cm -1).

AB - A vanadium(III) complex with N-hydroxyethyliminodiacetate (heida(3-)) was prepared. The X-ray crystallography has revealed that the compound is a dinuclear vanadium(III) complex, which contains a di-μ-alkoxo bridge derived from the deprotonation of the hydroxyethyl group of the parent heida(2-) ligand. Each vanadium(III) center adopts a distorted octahedral structure. The temperature-dependent magnetic susceptibility measurement suggests that the electronic spin moments of the two vanadium(III) centers are antiferro-magnetically coupled (g = 1.98 and J = - 36.9 cm -1).

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U2 - 10.1246/bcsj.74.2377

DO - 10.1246/bcsj.74.2377

M3 - 学術論文

AN - SCOPUS:0035693634

SN - 0009-2673

VL - 74

SP - 2377

EP - 2378

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 12

ER -

Synthesis, structure, and magnetic property of a dinuclear vanadium(III) complexes with N-hydroxyethyliminodiacetate

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