Synthesis of poison-frog alkaloids 233A, 235U, and 251AA and their inhibitory effects on neuronal nicotinic acetylcholine receptors

Naoki Toyooka*, Soushi Kobayashi, Dejun Zhou, Hiroshi Tsuneki, Tsutomu Wada, Hideki Sakai, Hideo Nemoto, Toshiyasu Sasaoka, H. Martin Garraffo, Thomas F. Spande, John W. Daly

*この論文の責任著者

研究成果: ジャーナルへの寄稿学術論文査読

30 被引用数 (Scopus)

抄録

We previously reported that the synthetic quinolizidine 1-epi-207I is a relatively selective blocker of α7 nicotinic acetylcholine receptors. We now synthesized the analogous poison frog alkaloids 233A, 235U, and 251AA, and investigated the biological activities at two major types of neuronal nicotinic receptors. Electrophysiological study showed that the alkaloid 233A blocked α7 and α4β2 currents with similar potencies. Alkaloids 235U and 251AA also showed similar potencies for blockade of α7 and α4β2 currents. Thus, based on these studies, it would appear that C4 substituents greater in length than the allyl of 1-epi-207I reduce α7-potency without affecting α4β2-potency.

本文言語英語
ページ(範囲)5872-5875
ページ数4
ジャーナルBioorganic and Medicinal Chemistry Letters
17
21
DOI
出版ステータス出版済み - 2007/11/01

ASJC Scopus 主題領域

  • 生化学
  • 分子医療
  • 分子生物学
  • 薬科学
  • 創薬
  • 臨床生化学
  • 有機化学

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