Synthesis of isoalkanes over Fe-Zn-Zr/HY composite catalyst through carbon dioxide hydrogenation

Xiaoming Ni; Yisheng Tan; Yizhuo Han; Noritatsu Tsubaki

doi:10.1016/j.catcom.2007.01.023

Synthesis of isoalkanes over Fe-Zn-Zr/HY composite catalyst through carbon dioxide hydrogenation

Xiaoming Ni, Yisheng Tan, Yizhuo Han^*, Noritatsu Tsubaki

^*この論文の責任著者

工学科　応用化学コース

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

47 被引用数 (Scopus)

抄録

The reaction path of isoalkanes formation via CO₂ hydrogenation was studied over the Fe-Zn-Zr/HY composite catalyst, which gives high selectivity to isoalkanes. The results indicate that the reverse water-gas shift reaction is not the indispensable step for the synthesis of hydrocarbons. And i-C₄ (iso-butane) is formed from propylene and methanol through MTG (methanol to gasoline) reaction and i-C₅ (iso-pentane) obtained from the reaction of C₂ and C₃ through the additive dimerization. A part of C₁, C₄ is formed on the sole Fe-Zn-Zr catalyst from methanol for the CO₂ hydrogenation over Fe-Zn-Zr/HY composite catalyst.

本文言語	英語
ページ（範囲）	1711-1714
ページ数	4
ジャーナル	Catalysis Communications
巻	8
号	11
DOI	https://doi.org/10.1016/j.catcom.2007.01.023
出版ステータス	出版済み - 2007/11

ASJC Scopus 主題領域

触媒
化学一般
プロセス化学およびプロセス工学

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10.1016/j.catcom.2007.01.023

引用スタイル

@article{ab7b94be82dd48d99f51277116c97440,

title = "Synthesis of isoalkanes over Fe-Zn-Zr/HY composite catalyst through carbon dioxide hydrogenation",

abstract = "The reaction path of isoalkanes formation via CO2 hydrogenation was studied over the Fe-Zn-Zr/HY composite catalyst, which gives high selectivity to isoalkanes. The results indicate that the reverse water-gas shift reaction is not the indispensable step for the synthesis of hydrocarbons. And i-C4 (iso-butane) is formed from propylene and methanol through MTG (methanol to gasoline) reaction and i-C5 (iso-pentane) obtained from the reaction of C2 and C3 through the additive dimerization. A part of C1, C4 is formed on the sole Fe-Zn-Zr catalyst from methanol for the CO2 hydrogenation over Fe-Zn-Zr/HY composite catalyst.",

keywords = "Carbon dioxide, Hydrogenation, Isoalkanes, Synthesis",

author = "Xiaoming Ni and Yisheng Tan and Yizhuo Han and Noritatsu Tsubaki",

note = "Funding Information: This work is financially supported by the National Natural Science Foundation of China (Project No. 29973056).",

year = "2007",

month = nov,

doi = "10.1016/j.catcom.2007.01.023",

language = "英語",

volume = "8",

pages = "1711--1714",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

number = "11",

}

TY - JOUR

T1 - Synthesis of isoalkanes over Fe-Zn-Zr/HY composite catalyst through carbon dioxide hydrogenation

AU - Ni, Xiaoming

AU - Tan, Yisheng

AU - Han, Yizhuo

AU - Tsubaki, Noritatsu

N1 - Funding Information: This work is financially supported by the National Natural Science Foundation of China (Project No. 29973056).

PY - 2007/11

Y1 - 2007/11

N2 - The reaction path of isoalkanes formation via CO2 hydrogenation was studied over the Fe-Zn-Zr/HY composite catalyst, which gives high selectivity to isoalkanes. The results indicate that the reverse water-gas shift reaction is not the indispensable step for the synthesis of hydrocarbons. And i-C4 (iso-butane) is formed from propylene and methanol through MTG (methanol to gasoline) reaction and i-C5 (iso-pentane) obtained from the reaction of C2 and C3 through the additive dimerization. A part of C1, C4 is formed on the sole Fe-Zn-Zr catalyst from methanol for the CO2 hydrogenation over Fe-Zn-Zr/HY composite catalyst.

AB - The reaction path of isoalkanes formation via CO2 hydrogenation was studied over the Fe-Zn-Zr/HY composite catalyst, which gives high selectivity to isoalkanes. The results indicate that the reverse water-gas shift reaction is not the indispensable step for the synthesis of hydrocarbons. And i-C4 (iso-butane) is formed from propylene and methanol through MTG (methanol to gasoline) reaction and i-C5 (iso-pentane) obtained from the reaction of C2 and C3 through the additive dimerization. A part of C1, C4 is formed on the sole Fe-Zn-Zr catalyst from methanol for the CO2 hydrogenation over Fe-Zn-Zr/HY composite catalyst.

KW - Carbon dioxide

KW - Hydrogenation

KW - Isoalkanes

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=34548680920&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2007.01.023

DO - 10.1016/j.catcom.2007.01.023

M3 - 学術論文

AN - SCOPUS:34548680920

SN - 1566-7367

VL - 8

SP - 1711

EP - 1714

JO - Catalysis Communications

JF - Catalysis Communications

IS - 11

ER -

Synthesis of isoalkanes over Fe-Zn-Zr/HY composite catalyst through carbon dioxide hydrogenation

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