Synthesis of a new compound, Ca0.8Ce1.2Sn2O7, with pyrochlore structure

Naoki Wakiya; Nobuo Kieda; Atsushi Saiki; Kazuo Shinozaki; Nobuyasu Mizutani

doi:10.1016/0022-4596(91)90340-N

Synthesis of a new compound, Ca_0.8Ce_1.2Sn₂O₇, with pyrochlore structure

Naoki Wakiya^*, Nobuo Kieda, Atsushi Saiki, Kazuo Shinozaki, Nobuyasu Mizutani

^*この論文の責任著者

材料デザイン工学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

10 被引用数 (Scopus)

抄録

A new compound of the formula Ca_2XCe_2-2XSn₂O₇, wherein 0.35 ≦ X ≦ 0.43, with cubic pyrochlore structure was synthesized by a solid state reaction at 1450°C. Rietveld analysis based on A site substitution gave evidence that this new compound belonged to Fd3m with cubic pyrochlore structure. It was expected from chemical analysis that some of the Ce ions at the A site should be trivalent to maintain electrical neutrality of the whole crystal. This expectation is justified by the description of average ionic radii in the A site of this new pyrochlore and the model of Rietveld analysis.

本文言語	英語
ページ（範囲）	320-326
ページ数	7
ジャーナル	Journal of Solid State Chemistry
巻	92
号	2
DOI	https://doi.org/10.1016/0022-4596(91)90340-N
出版ステータス	出版済み - 1991/06

ASJC Scopus 主題領域

電子材料、光学材料、および磁性材料
セラミックおよび複合材料
凝縮系物理学
物理化学および理論化学
無機化学
材料化学

文献へのアクセス

10.1016/0022-4596(91)90340-N

引用スタイル

@article{29889f2e057c4839b7a0b2b1fee839b4,

title = "Synthesis of a new compound, Ca0.8Ce1.2Sn2O7, with pyrochlore structure",

abstract = "A new compound of the formula Ca2XCe2-2XSn2O7, wherein 0.35 ≦ X ≦ 0.43, with cubic pyrochlore structure was synthesized by a solid state reaction at 1450°C. Rietveld analysis based on A site substitution gave evidence that this new compound belonged to Fd3m with cubic pyrochlore structure. It was expected from chemical analysis that some of the Ce ions at the A site should be trivalent to maintain electrical neutrality of the whole crystal. This expectation is justified by the description of average ionic radii in the A site of this new pyrochlore and the model of Rietveld analysis.",

author = "Naoki Wakiya and Nobuo Kieda and Atsushi Saiki and Kazuo Shinozaki and Nobuyasu Mizutani",

year = "1991",

month = jun,

doi = "10.1016/0022-4596(91)90340-N",

language = "英語",

volume = "92",

pages = "320--326",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "2",

}

TY - JOUR

T1 - Synthesis of a new compound, Ca0.8Ce1.2Sn2O7, with pyrochlore structure

AU - Wakiya, Naoki

AU - Kieda, Nobuo

AU - Saiki, Atsushi

AU - Shinozaki, Kazuo

AU - Mizutani, Nobuyasu

PY - 1991/6

Y1 - 1991/6

N2 - A new compound of the formula Ca2XCe2-2XSn2O7, wherein 0.35 ≦ X ≦ 0.43, with cubic pyrochlore structure was synthesized by a solid state reaction at 1450°C. Rietveld analysis based on A site substitution gave evidence that this new compound belonged to Fd3m with cubic pyrochlore structure. It was expected from chemical analysis that some of the Ce ions at the A site should be trivalent to maintain electrical neutrality of the whole crystal. This expectation is justified by the description of average ionic radii in the A site of this new pyrochlore and the model of Rietveld analysis.

AB - A new compound of the formula Ca2XCe2-2XSn2O7, wherein 0.35 ≦ X ≦ 0.43, with cubic pyrochlore structure was synthesized by a solid state reaction at 1450°C. Rietveld analysis based on A site substitution gave evidence that this new compound belonged to Fd3m with cubic pyrochlore structure. It was expected from chemical analysis that some of the Ce ions at the A site should be trivalent to maintain electrical neutrality of the whole crystal. This expectation is justified by the description of average ionic radii in the A site of this new pyrochlore and the model of Rietveld analysis.

UR - http://www.scopus.com/inward/record.url?scp=0042030839&partnerID=8YFLogxK

U2 - 10.1016/0022-4596(91)90340-N

DO - 10.1016/0022-4596(91)90340-N

M3 - 学術論文

AN - SCOPUS:0042030839

SN - 0022-4596

VL - 92

SP - 320

EP - 326

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Synthesis of a new compound, Ca0.8Ce1.2Sn2O7, with pyrochlore structure

抄録

ASJC Scopus 主題領域

文献へのアクセス

フィンガープリント

引用スタイル

Synthesis of a new compound, Ca_0.8Ce_1.2Sn₂O₇, with pyrochlore structure