TY - JOUR
T1 - Synthesis and structure of a neutral Au I 4Ni II 2 hexanuclear complex containing D-penicillaminate and 1,2-bis(diphenylphosphino)ethane
AU - Igashira-Kamiyama, Asako
AU - Matsushita, Natsuko
AU - Lee, Raeeun
AU - Tsuge, Kiyoshi
AU - Konno, Takumi
PY - 2012
Y1 - 2012
N2 - The 1:1 reaction of [Au 2(dppe)(D-Hpen) 2] (dppe: 1,2-bis(diphenylphosphino)ethane, D-H 2pen: D-penicillamine) with Ni(CH 3COO) 2·4H 2O in ethanol, followed by the vapor diffusion of diethyl ether, gave blue-green crystals of [Au 4Ni 2(dppe) 2(D-pen) 4]. This compound showed singlecrystalto-single-crystal conversion on soaking in water, accompanied by the drastic change in complex-molecular arrangements from straight chain to helix structures.
AB - The 1:1 reaction of [Au 2(dppe)(D-Hpen) 2] (dppe: 1,2-bis(diphenylphosphino)ethane, D-H 2pen: D-penicillamine) with Ni(CH 3COO) 2·4H 2O in ethanol, followed by the vapor diffusion of diethyl ether, gave blue-green crystals of [Au 4Ni 2(dppe) 2(D-pen) 4]. This compound showed singlecrystalto-single-crystal conversion on soaking in water, accompanied by the drastic change in complex-molecular arrangements from straight chain to helix structures.
UR - http://www.scopus.com/inward/record.url?scp=84862544917&partnerID=8YFLogxK
U2 - 10.1246/bcsj.20120024
DO - 10.1246/bcsj.20120024
M3 - 学術論文
AN - SCOPUS:84862544917
SN - 0009-2673
VL - 85
SP - 706
EP - 708
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 6
ER -