Synthesis and reactions of 1,1-trimethylene-1H-azulenium ion

Mitsunori Oda; Aya Sakamoto; Ryuta Miyatake; Shigeyasu Kuroda

doi:10.1016/S0040-4039(98)01273-8

Synthesis and reactions of 1,1-trimethylene-1H-azulenium ion

Mitsunori Oda^*, Aya Sakamoto, Ryuta Miyatake, Shigeyasu Kuroda

^*この論文の責任著者

環境安全推進センター

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

10 被引用数 (Scopus)

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Direct cyclobutylation of 1,6-dihydroazulene gave the spiro hydrocarbon 6, which was subjected to hydride abstraction to lead to the title cation 4. Its hexafluorophosphate salt was isolated as crystals. The cation 4 showed distinctive chemical behavior compared with its three-membered ring homolog.

本文言語	英語
ページ（範囲）	6195-6198
ページ数	4
ジャーナル	Tetrahedron Letters
巻	39
号	34
DOI	https://doi.org/10.1016/S0040-4039(98)01273-8
出版ステータス	出版済み - 1998/08/20

ASJC Scopus 主題領域

生化学
創薬
有機化学

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10.1016/S0040-4039(98)01273-8

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title = "Synthesis and reactions of 1,1-trimethylene-1H-azulenium ion",

abstract = "Direct cyclobutylation of 1,6-dihydroazulene gave the spiro hydrocarbon 6, which was subjected to hydride abstraction to lead to the title cation 4. Its hexafluorophosphate salt was isolated as crystals. The cation 4 showed distinctive chemical behavior compared with its three-membered ring homolog.",

keywords = "Carbocations, Rearrangements, Spiro compounds, Tropylium ions",

author = "Mitsunori Oda and Aya Sakamoto and Ryuta Miyatake and Shigeyasu Kuroda",

year = "1998",

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doi = "10.1016/S0040-4039(98)01273-8",

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T1 - Synthesis and reactions of 1,1-trimethylene-1H-azulenium ion

AU - Oda, Mitsunori

AU - Sakamoto, Aya

AU - Miyatake, Ryuta

AU - Kuroda, Shigeyasu

PY - 1998/8/20

Y1 - 1998/8/20

N2 - Direct cyclobutylation of 1,6-dihydroazulene gave the spiro hydrocarbon 6, which was subjected to hydride abstraction to lead to the title cation 4. Its hexafluorophosphate salt was isolated as crystals. The cation 4 showed distinctive chemical behavior compared with its three-membered ring homolog.

AB - Direct cyclobutylation of 1,6-dihydroazulene gave the spiro hydrocarbon 6, which was subjected to hydride abstraction to lead to the title cation 4. Its hexafluorophosphate salt was isolated as crystals. The cation 4 showed distinctive chemical behavior compared with its three-membered ring homolog.

KW - Carbocations

KW - Rearrangements

KW - Spiro compounds

KW - Tropylium ions

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U2 - 10.1016/S0040-4039(98)01273-8

DO - 10.1016/S0040-4039(98)01273-8

M3 - 学術論文

AN - SCOPUS:0032552126

SN - 0040-4039

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JO - Tetrahedron Letters

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Synthesis and reactions of 1,1-trimethylene-1H-azulenium ion

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