Synthesis and properties of anti, anti-8,17-epithia-1,6;10,15- bismethano[18]annulene-7,18-dione and its dicationic species

Shigeyasu Kuroda*, Mitsunori Oda, Shin Ya Kuramoto, Atsushi Fukuta, Yoshihiro Mizukami, Yoshihiko Nozawa, Ryuta Miyatake, Mayumi Izawa, Ichiro Shimao

*この論文の責任著者

研究成果: ジャーナルへの寄稿学術論文査読

2 被引用数 (Scopus)

抄録

The titled quinone compound has been synthesized, and the X-ray crystallographic analysis of this compound revealed that it has anti-anti- configuration for stereochemical relationship between two methylene and sulfur bridges. Its 1H and 13C NMR spectra in D2SO4 indicate that the cationic species formed by protonation has localized positive charges on the carbony carbons, mainly due to the unfavorable p-orbital overlap.

本文言語英語
ページ(範囲)8291-8294
ページ数4
ジャーナルTetrahedron Letters
38
48
DOI
出版ステータス出版済み - 1997/12/01

ASJC Scopus 主題領域

  • 生化学
  • 創薬
  • 有機化学

フィンガープリント

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