Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

Bayu Ardiansah; Hiroki Tanimoto; Takenori Tomohiro; Tsumoru Morimoto; Kiyomi Kakiuchi

doi:10.1039/d1cc02770k

Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

Bayu Ardiansah, Hiroki Tanimoto^*, Takenori Tomohiro, Tsumoru Morimoto, Kiyomi Kakiuchi

^*この論文の責任著者

生体認識化学研究室

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

12 被引用数 (Scopus)

抄録

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.

本文言語	英語
ページ（範囲）	8738-8741
ページ数	4
ジャーナル	Chemical Communications
巻	57
号	70
DOI	https://doi.org/10.1039/d1cc02770k
出版ステータス	出版済み - 2021/09/11

ASJC Scopus 主題領域

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学一般
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/d1cc02770k

引用スタイル

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title = "Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides",

abstract = "Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.",

author = "Bayu Ardiansah and Hiroki Tanimoto and Takenori Tomohiro and Tsumoru Morimoto and Kiyomi Kakiuchi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = sep,

day = "11",

doi = "10.1039/d1cc02770k",

language = "英語",

volume = "57",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

AU - Ardiansah, Bayu

AU - Tanimoto, Hiroki

AU - Tomohiro, Takenori

AU - Morimoto, Tsumoru

AU - Kakiuchi, Kiyomi

PY - 2021/9/11

Y1 - 2021/9/11

N2 - Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.

AB - Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.

UR - http://www.scopus.com/inward/record.url?scp=85114301850&partnerID=8YFLogxK

U2 - 10.1039/d1cc02770k

DO - 10.1039/d1cc02770k

M3 - 学術論文

C2 - 34374377

AN - SCOPUS:85114301850

SN - 1359-7345

VL - 57

SP - 8738

EP - 8741

JO - Chemical Communications

JF - Chemical Communications

IS - 70

ER -

Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

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