Studies toward intramolecular cycloaddition of o-quinodimethane with an oxazole moiety

Yuji Matsuya; Hongbo Qin; Hideo Nemoto

doi:10.3987/COM-08-S(D)43

Studies toward intramolecular cycloaddition of o-quinodimethane with an oxazole moiety

Yuji Matsuya^*, Hongbo Qin, Hideo Nemoto

^*この論文の責任著者

薬品製造学研究室

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

3 被引用数 (Scopus)

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Thermal reaction of benzocyclobutene derivatives having an oxazole moiety was investigated. Intramolecular [4+2] cycloaddition of o-quinodimethane, generated by thermolysis of the benzocyclobutene, with the oxazole did not proceed, and instead, [1,5]-sigmatropic rearrangement occurred dominantly.

本文言語	英語
ページ（範囲）	773-779
ページ数	7
ジャーナル	Heterocycles
巻	79
号	C
DOI	https://doi.org/10.3987/COM-08-S(D)43
出版ステータス	出版済み - 2009

ASJC Scopus 主題領域

分析化学
薬理学
有機化学

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10.3987/COM-08-S(D)43

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title = "Studies toward intramolecular cycloaddition of o-quinodimethane with an oxazole moiety",

abstract = "Thermal reaction of benzocyclobutene derivatives having an oxazole moiety was investigated. Intramolecular [4+2] cycloaddition of o-quinodimethane, generated by thermolysis of the benzocyclobutene, with the oxazole did not proceed, and instead, [1,5]-sigmatropic rearrangement occurred dominantly.",

keywords = "Benzocyclobutene, Cycloaddition, Oxazole, Rearrangement, o-Quinodimethane",

author = "Yuji Matsuya and Hongbo Qin and Hideo Nemoto",

year = "2009",

doi = "10.3987/COM-08-S(D)43",

language = "英語",

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T1 - Studies toward intramolecular cycloaddition of o-quinodimethane with an oxazole moiety

AU - Matsuya, Yuji

AU - Qin, Hongbo

AU - Nemoto, Hideo

PY - 2009

Y1 - 2009

N2 - Thermal reaction of benzocyclobutene derivatives having an oxazole moiety was investigated. Intramolecular [4+2] cycloaddition of o-quinodimethane, generated by thermolysis of the benzocyclobutene, with the oxazole did not proceed, and instead, [1,5]-sigmatropic rearrangement occurred dominantly.

AB - Thermal reaction of benzocyclobutene derivatives having an oxazole moiety was investigated. Intramolecular [4+2] cycloaddition of o-quinodimethane, generated by thermolysis of the benzocyclobutene, with the oxazole did not proceed, and instead, [1,5]-sigmatropic rearrangement occurred dominantly.

KW - Benzocyclobutene

KW - Cycloaddition

KW - Oxazole

KW - Rearrangement

KW - o-Quinodimethane

UR - http://www.scopus.com/inward/record.url?scp=67651109000&partnerID=8YFLogxK

U2 - 10.3987/COM-08-S(D)43

DO - 10.3987/COM-08-S(D)43

M3 - 学術論文

AN - SCOPUS:67651109000

SN - 0385-5414

VL - 79

SP - 773

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JO - Heterocycles

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Studies toward intramolecular cycloaddition of o-quinodimethane with an oxazole moiety

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