Stereoselective reduction of α-alkoxy acetylenic ketones with zinc borohydride and K-selectride.

Takashi Takahashi; Masahiro Miyazawa; Jiro Tsuji

doi:10.1016/S0040-4039(00)98885-3

Stereoselective reduction of α-alkoxy acetylenic ketones with zinc borohydride and K-selectride.

Takashi Takahashi, Masahiro Miyazawa, Jiro Tsuji

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

61 被引用数 (Scopus)

抄録

Reduction of α-benzyloxy acetylenic ketones with zinc borohydride afforded the erythro-acetylenic vicinal diols in 95% stereoselectivity, while reduction with K-selectride gave the isomeric threo-diols in 90% stereoselectivity.

本文言語	英語
ページ（範囲）	5139-5142
ページ数	4
ジャーナル	Tetrahedron Letters
巻	26
号	42
DOI	https://doi.org/10.1016/S0040-4039(00)98885-3
出版ステータス	出版済み - 1985

ASJC Scopus 主題領域

生化学
創薬
有機化学

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10.1016/S0040-4039(00)98885-3

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@article{4046e373e1d74528a53fb7ec4ca3fafe,

title = "Stereoselective reduction of α-alkoxy acetylenic ketones with zinc borohydride and K-selectride.",

abstract = "Reduction of α-benzyloxy acetylenic ketones with zinc borohydride afforded the erythro-acetylenic vicinal diols in 95% stereoselectivity, while reduction with K-selectride gave the isomeric threo-diols in 90% stereoselectivity.",

author = "Takashi Takahashi and Masahiro Miyazawa and Jiro Tsuji",

year = "1985",

doi = "10.1016/S0040-4039(00)98885-3",

language = "英語",

volume = "26",

pages = "5139--5142",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd.",

number = "42",

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TY - JOUR

T1 - Stereoselective reduction of α-alkoxy acetylenic ketones with zinc borohydride and K-selectride.

AU - Takahashi, Takashi

AU - Miyazawa, Masahiro

AU - Tsuji, Jiro

PY - 1985

Y1 - 1985

N2 - Reduction of α-benzyloxy acetylenic ketones with zinc borohydride afforded the erythro-acetylenic vicinal diols in 95% stereoselectivity, while reduction with K-selectride gave the isomeric threo-diols in 90% stereoselectivity.

AB - Reduction of α-benzyloxy acetylenic ketones with zinc borohydride afforded the erythro-acetylenic vicinal diols in 95% stereoselectivity, while reduction with K-selectride gave the isomeric threo-diols in 90% stereoselectivity.

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U2 - 10.1016/S0040-4039(00)98885-3

DO - 10.1016/S0040-4039(00)98885-3

M3 - 学術論文

AN - SCOPUS:0000633376

SN - 0040-4039

VL - 26

SP - 5139

EP - 5142

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 42

ER -

Stereoselective reduction of α-alkoxy acetylenic ketones with zinc borohydride and K-selectride.

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ASJC Scopus 主題領域

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