Solid-state transformation of achiral crystals to a chiral crystal by guest release from host-guest inclusion crystals of achiral host compound

Hironori Saito; Mitsuaki Suzuki; Hiroshi Miyamae; Naoto Hayashi; Keiji Kobayashi

doi:10.1246/cl.2009.1080

Solid-state transformation of achiral crystals to a chiral crystal by guest release from host-guest inclusion crystals of achiral host compound

Hironori Saito^*, Mitsuaki Suzuki, Hiroshi Miyamae, Naoto Hayashi, Keiji Kobayashi

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

2 被引用数 (Scopus)

抄録

Solid-state transformation of achiral crystals into a chiral crystal was induced by thermal guest release from the host-guest inclusion complexes of 2,5-bis(hydroxydiphenyImethyl)thieno[3,2-è]thiophene as a host component. The chilarity of the resulting guest-free crystals, also obtained by recrystallization from dichloromethane, is attributed to conformational freezing of the achiral molecule into a chiral molecular structure in the solid state.

本文言語	英語
ページ（範囲）	1080-1081
ページ数	2
ジャーナル	Chemistry Letters
巻	38
号	11
DOI	https://doi.org/10.1246/cl.2009.1080
出版ステータス	出版済み - 2009

ASJC Scopus 主題領域

化学一般

文献へのアクセス

10.1246/cl.2009.1080

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引用スタイル

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abstract = "Solid-state transformation of achiral crystals into a chiral crystal was induced by thermal guest release from the host-guest inclusion complexes of 2,5-bis(hydroxydiphenyImethyl)thieno[3,2-{\`e}]thiophene as a host component. The chilarity of the resulting guest-free crystals, also obtained by recrystallization from dichloromethane, is attributed to conformational freezing of the achiral molecule into a chiral molecular structure in the solid state.",

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AU - Saito, Hironori

AU - Suzuki, Mitsuaki

AU - Miyamae, Hiroshi

AU - Hayashi, Naoto

AU - Kobayashi, Keiji

PY - 2009

Y1 - 2009

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AB - Solid-state transformation of achiral crystals into a chiral crystal was induced by thermal guest release from the host-guest inclusion complexes of 2,5-bis(hydroxydiphenyImethyl)thieno[3,2-è]thiophene as a host component. The chilarity of the resulting guest-free crystals, also obtained by recrystallization from dichloromethane, is attributed to conformational freezing of the achiral molecule into a chiral molecular structure in the solid state.

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U2 - 10.1246/cl.2009.1080

DO - 10.1246/cl.2009.1080

M3 - 学術論文

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