抄録
An amphiphilic pyridine–phenol alternating oligomer, in which oligo(ethylene glycol) chains are attached at the 4-positions of the pyridine and the phenol rings, was synthesized as a helical host to realize saccharide recognition in water. This oligomer was soluble not only in less-polar solvents but also in water at room temperature. Circular dichroism investigations revealed that the oligomer could recognize several kinds of saccharides and their derivatives, including glycodrugs to form chiral higher-order structures in water. Especially, the oligomer showed high affinity for d-glucosamine, and their association constants were over 103 m–1.
| 本文言語 | 英語 |
|---|---|
| ページ（範囲） | 6975-6979 |
| ページ数 | 5 |
| ジャーナル | European Journal of Organic Chemistry |
| 巻 | 2017 |
| 号 | 46 |
| DOI | |
| 出版ステータス | 出版済み - 2017/12/15 |
ASJC Scopus 主題領域
- 物理化学および理論化学
- 有機化学