@article{34168cfce11d423e86fa1720839151e8,
title = "Rhodium(I)-Catalyzed Carbonylative Annulation of Iodobenzenes with Strained Olefins and 4-Octyne in the Presence of Furfural Involving ortho-C–H Bond Cleavage",
abstract = "The rhodium(I)-catalyzed carbonylative annulation of iodobenzenes with strained olefins in the presence of furfural as a carbonyl source, accompanied by ortho-C–H bond cleavage, is reported. The use of 4-octyne in place of strained olefins also leads to the formation of the corresponding inden-9-one. The timely release of the carbonyl moiety via the rhodium-catalyzed decarbonylation of furfural plays a decisive role in this reaction. (Figure presented.).",
keywords = "C–H functionalization, carbonylative annulation, furfural, rhodium catalyst, three-component reactions",
author = "Takuma Furusawa and Hiroki Tanimoto and Yasuhiro Nishiyama and Tsumoru Morimoto and Kiyomi Kakiuchi",
note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2017",
month = jan,
day = "19",
doi = "10.1002/adsc.201601056",
language = "英語",
volume = "359",
pages = "240--245",
journal = "Advanced Synthesis and Catalysis",
issn = "1615-4150",
publisher = "Wiley-VCH Verlag",
number = "2",
}