抄録
The relationships between structure and reactivity of thiophene derivatives were studied with different degrees of aromatic condensation and numbers of methyl groups. Reactivity of benzothiophene was lower compared to dibenzothiophene (DBT), whereas reactivity of benzonaphthothiophene was like that of DBT. Reactivity of 2-methybenzothiophene was higher than that of benzothiophene. Methyl group at the 2-position of benzothiophene caused no steric hindrance to approach of the oxidants. Methyl groups at the 4- and/or 6-positions of DBT showed different effects depending on the reaction conditions and the nature of the active species.
本文言語 | 英語 |
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ページ(範囲) | 142-148 |
ページ数 | 7 |
ジャーナル | Journal of the Japan Petroleum Institute |
巻 | 66 |
号 | 5 |
DOI | |
出版ステータス | 出版済み - 2023 |
ASJC Scopus 主題領域
- 燃料技術
- エネルギー工学および電力技術