Relationships between Structures and Reactivities in the Oxidation of Benzothiophene and Dibenzothiophene Derivatives

Satoru Murata*, Taichi Nakai, Masahiko Hatakeyama, Satoshi Sunada

*この論文の責任著者

研究成果: ジャーナルへの寄稿学術論文査読

2 被引用数 (Scopus)

抄録

The relationships between structure and reactivity of thiophene derivatives were studied with different degrees of aromatic condensation and numbers of methyl groups. Reactivity of benzothiophene was lower compared to dibenzothiophene (DBT), whereas reactivity of benzonaphthothiophene was like that of DBT. Reactivity of 2-methybenzothiophene was higher than that of benzothiophene. Methyl group at the 2-position of benzothiophene caused no steric hindrance to approach of the oxidants. Methyl groups at the 4- and/or 6-positions of DBT showed different effects depending on the reaction conditions and the nature of the active species.

本文言語英語
ページ(範囲)142-148
ページ数7
ジャーナルJournal of the Japan Petroleum Institute
66
5
DOI
出版ステータス出版済み - 2023

ASJC Scopus 主題領域

  • 燃料技術
  • エネルギー工学および電力技術

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