Recent advances in the catalytic fixation of carbon dioxide to value-added chemicals over alkali metal salts

Cong Chien Truong*, Dinesh Kumar Mishra*

*この論文の責任著者

研究成果: ジャーナルへの寄稿総説査読

53 被引用数 (Scopus)

抄録

Currently, carbon dioxide (CO2) is regarded as a renewable C1 feedstock for the mass production of several products such as ureas, carbamates, carbonates, carboxylic acid derivatives, polymers, etc. Moreover, a collection of biological heterocycles with diversified frameworks derived from the fixation of CO2 are also detected. In such transformations, expensive catalyst systems (e.g. transitional metal complexes, and task-specific ionic liquids), additives, and harsh reaction conditions have been deployed, respectively. In contrast, cheap and easy-to-handle alkali metal salts have been recently explored as powerful catalysts in the transformation of CO2 at milder and greener conditions. In this review, we cover a thorough overview of alkali metal salt-mediated fixation of CO2 into different classes of value-added products. Furthermore, the detailed reaction mechanisms as well as the excellency of these alkali metal catalysts in terms of stability, recyclability are also addressed.

本文言語英語
論文番号101252
ジャーナルJournal of CO2 Utilization
41
DOI
出版ステータス出版済み - 2020/10

ASJC Scopus 主題領域

  • 化学工学(その他)
  • 廃棄物管理と処理
  • プロセス化学およびプロセス工学

フィンガープリント

「Recent advances in the catalytic fixation of carbon dioxide to value-added chemicals over alkali metal salts」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル