Rearrangements of tricyclo[5.3.1.0]undecatrienyl anion; chemical evidence supporting cyclopropane ring circumambulation of anionic species

Mitsunori Oda; Yoshimi Masaki; Yoshimi Okazaki; Takanori Kajioka; Mayumi Izawa; Ryuta Miyatake; Shigeyasu Kuroda; Lawrence T. Scott

doi:10.1246/cl.1997.595

Rearrangements of tricyclo[5.3.1.0]undecatrienyl anion; chemical evidence supporting cyclopropane ring circumambulation of anionic species

Mitsunori Oda^*, Yoshimi Masaki, Yoshimi Okazaki, Takanori Kajioka, Mayumi Izawa, Ryuta Miyatake, Shigeyasu Kuroda, Lawrence T. Scott

^*この論文の責任著者

環境安全推進センター

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

2 被引用数 (Scopus)

抄録

The tricyclic anion 5, generated from the corresponding hydrocarbon 3 with n-BuLi, undergoes the circumambulatory rearrangement at -78°C to afford the anion 6, which stereo-selectively reacts with deuterium oxide at low temperature and undergoes further rearrangements to the stable cyclopentadienyl anion derivative 9 at elevated temperature.

本文言語	英語
ページ（範囲）	595-596
ページ数	2
ジャーナル	Chemistry Letters
号	7
DOI	https://doi.org/10.1246/cl.1997.595
出版ステータス	出版済み - 1997

ASJC Scopus 主題領域

化学一般

文献へのアクセス

10.1246/cl.1997.595

フィンガープリント

「Rearrangements of tricyclo[5.3.1.0]undecatrienyl anion; chemical evidence supporting cyclopropane ring circumambulation of anionic species」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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title = "Rearrangements of tricyclo[5.3.1.0]undecatrienyl anion; chemical evidence supporting cyclopropane ring circumambulation of anionic species",

abstract = "The tricyclic anion 5, generated from the corresponding hydrocarbon 3 with n-BuLi, undergoes the circumambulatory rearrangement at -78°C to afford the anion 6, which stereo-selectively reacts with deuterium oxide at low temperature and undergoes further rearrangements to the stable cyclopentadienyl anion derivative 9 at elevated temperature.",

author = "Mitsunori Oda and Yoshimi Masaki and Yoshimi Okazaki and Takanori Kajioka and Mayumi Izawa and Ryuta Miyatake and Shigeyasu Kuroda and Scott, {Lawrence T.}",

year = "1997",

doi = "10.1246/cl.1997.595",

language = "英語",

pages = "595--596",

journal = "Chemistry Letters",

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T1 - Rearrangements of tricyclo[5.3.1.0]undecatrienyl anion; chemical evidence supporting cyclopropane ring circumambulation of anionic species

AU - Oda, Mitsunori

AU - Masaki, Yoshimi

AU - Okazaki, Yoshimi

AU - Kajioka, Takanori

AU - Izawa, Mayumi

AU - Miyatake, Ryuta

AU - Kuroda, Shigeyasu

AU - Scott, Lawrence T.

PY - 1997

Y1 - 1997

N2 - The tricyclic anion 5, generated from the corresponding hydrocarbon 3 with n-BuLi, undergoes the circumambulatory rearrangement at -78°C to afford the anion 6, which stereo-selectively reacts with deuterium oxide at low temperature and undergoes further rearrangements to the stable cyclopentadienyl anion derivative 9 at elevated temperature.

AB - The tricyclic anion 5, generated from the corresponding hydrocarbon 3 with n-BuLi, undergoes the circumambulatory rearrangement at -78°C to afford the anion 6, which stereo-selectively reacts with deuterium oxide at low temperature and undergoes further rearrangements to the stable cyclopentadienyl anion derivative 9 at elevated temperature.

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U2 - 10.1246/cl.1997.595

DO - 10.1246/cl.1997.595

M3 - 学術論文

AN - SCOPUS:0031486794

SN - 0366-7022

SP - 595

EP - 596

JO - Chemistry Letters

JF - Chemistry Letters

IS - 7

ER -