Preparation and spectroscopic study of alternate meta-ethynylpyridine oligomer involving 2,4,6-trisubstituted and 3,5-disubstituted pyridine rings

Hajime Abe; Daiki Suzuki; Ayako Shimizu; Masahiko Inouye

doi:10.3987/COM-13-S(S)78

Preparation and spectroscopic study of alternate meta-ethynylpyridine oligomer involving 2,4,6-trisubstituted and 3,5-disubstituted pyridine rings

Hajime Abe^*, Daiki Suzuki, Ayako Shimizu, Masahiko Inouye

^*この論文の責任著者

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研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

4 被引用数 (Scopus)

抄録

A new type of ethynylpyridine cooligomer which consists of 3,5- and 2,6-pyridylene units alternately linked with acetylene bonds was prepared by repeating Sonogashira reaction. ¹H NMR study suggested that this cooligomer associates with methanol by hydrogen-bonding at the pyridine units. Intramolecular excimer emission was observed around 540 nm by fluorescence measurement, indicating the formation of helical conformation. Weak induced CD was observed by the addition of octyl glucoside as a guest.

本文言語	英語
ページ（範囲）	547-557
ページ数	11
ジャーナル	Heterocycles
巻	88
号	1
DOI	https://doi.org/10.3987/COM-13-S(S)78
出版ステータス	出版済み - 2014

ASJC Scopus 主題領域

分析化学
薬理学
有機化学

文献へのアクセス

10.3987/COM-13-S(S)78

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引用スタイル

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abstract = "A new type of ethynylpyridine cooligomer which consists of 3,5- and 2,6-pyridylene units alternately linked with acetylene bonds was prepared by repeating Sonogashira reaction. 1H NMR study suggested that this cooligomer associates with methanol by hydrogen-bonding at the pyridine units. Intramolecular excimer emission was observed around 540 nm by fluorescence measurement, indicating the formation of helical conformation. Weak induced CD was observed by the addition of octyl glucoside as a guest.",

author = "Hajime Abe and Daiki Suzuki and Ayako Shimizu and Masahiko Inouye",

note = "Publisher Copyright: {\textcopyright} 2014 The Japan Institute of Heterocyclic Chemistry.",

year = "2014",

doi = "10.3987/COM-13-S(S)78",

language = "英語",

volume = "88",

pages = "547--557",

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AU - Shimizu, Ayako

AU - Inouye, Masahiko

PY - 2014

Y1 - 2014

N2 - A new type of ethynylpyridine cooligomer which consists of 3,5- and 2,6-pyridylene units alternately linked with acetylene bonds was prepared by repeating Sonogashira reaction. 1H NMR study suggested that this cooligomer associates with methanol by hydrogen-bonding at the pyridine units. Intramolecular excimer emission was observed around 540 nm by fluorescence measurement, indicating the formation of helical conformation. Weak induced CD was observed by the addition of octyl glucoside as a guest.

AB - A new type of ethynylpyridine cooligomer which consists of 3,5- and 2,6-pyridylene units alternately linked with acetylene bonds was prepared by repeating Sonogashira reaction. 1H NMR study suggested that this cooligomer associates with methanol by hydrogen-bonding at the pyridine units. Intramolecular excimer emission was observed around 540 nm by fluorescence measurement, indicating the formation of helical conformation. Weak induced CD was observed by the addition of octyl glucoside as a guest.

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DO - 10.3987/COM-13-S(S)78

M3 - 学術論文

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