Preferential Recognition and Extraction to Pentoses over Hexoses by a D6 h-Symmetrical Ethynylphenol Macrocycle with Six Inner Phenolic Hydroxy Groups

Tomoya Hayashi; Yuki Ohishi; Hajime Abe; Masahiko Inouye

doi:10.1021/acs.joc.9b02639

Preferential Recognition and Extraction to Pentoses over Hexoses by a D_{6 h}-Symmetrical Ethynylphenol Macrocycle with Six Inner Phenolic Hydroxy Groups

Tomoya Hayashi, Yuki Ohishi^*, Hajime Abe, Masahiko Inouye^*

^*この論文の責任著者

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

12 被引用数 (Scopus)

抄録

A macrocycle consisting of six ethynylphenol units was developed as a host architecture for saccharides. The rigid framework of the macrocycle suppressed the intramolecular hydrogen-bonding between adjacent phenolic hydroxy groups and recognized saccharides by intermolecular hydrogen-bonding within the hole. The well-defined hydrogen-bonding sites enabled the size-selective guest recognition and showed preference to pentoses over hexoses.

本文言語	英語
ページ（範囲）	1927-1934
ページ数	8
ジャーナル	Journal of Organic Chemistry
巻	85
号	4
DOI	https://doi.org/10.1021/acs.joc.9b02639
出版ステータス	出版済み - 2020/02/21

ASJC Scopus 主題領域

有機化学

文献へのアクセス

10.1021/acs.joc.9b02639

フィンガープリント

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引用スタイル

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abstract = "A macrocycle consisting of six ethynylphenol units was developed as a host architecture for saccharides. The rigid framework of the macrocycle suppressed the intramolecular hydrogen-bonding between adjacent phenolic hydroxy groups and recognized saccharides by intermolecular hydrogen-bonding within the hole. The well-defined hydrogen-bonding sites enabled the size-selective guest recognition and showed preference to pentoses over hexoses.",

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AU - Inouye, Masahiko

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