Practical and environmentally friendly transformation of tetrahydrofuran- 2-methanols to γ-lactones via oxidative cleavage

Tomoya Fujiwara; Yuto Horiuchi; Akihiro Yamada; Hisanori Nambu; Takayuki Yakura

doi:10.1007/978-981-10-3421-3_13

Practical and environmentally friendly transformation of tetrahydrofuran- 2-methanols to γ-lactones via oxidative cleavage

Tomoya Fujiwara, Yuto Horiuchi, Akihiro Yamada, Hisanori Nambu, Takayuki Yakura^*

^*この論文の責任著者

分子合成化学研究室

研究成果: 書籍の章/レポート/会議録 › 章 › 査読

2 被引用数 (Scopus)

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Transformation of oxacycle-2-methanols to the corresponding lactones is often applied to total synthesis of natural products. It is accomplished by either direct oxidative cleavage reaction using a heavy metal oxidant or multistep conversion. As a practical and environmentally friendly procedure, a direct oxidative cleavage reaction of tetrahydrofuran-2-methanols to the corresponding c-lactones was developed. This new catalytic reaction proceeds with a catalytic amount of 2-iodobenzamide and stoichiometric Oxone (2KHSO₅.KHSO₄.K2SO₄) at room temperature.

本文言語	英語
ホスト出版物のタイトル	New Horizons of Process Chemistry
ホスト出版物のサブタイトル	Scalable Reactions and Technologies
出版社	Springer Singapore
ページ	179-190
ページ数	12
ISBN（電子版）	9789811034213
ISBN（印刷版）	9789811034206
DOI	https://doi.org/10.1007/978-981-10-3421-3_13
出版ステータス	出版済み - 2017/01/01

ASJC Scopus 主題領域

化学一般
化学工学一般
医学一般
工学一般
農業および生物科学一般

文献へのアクセス

10.1007/978-981-10-3421-3_13

引用スタイル

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abstract = "Transformation of oxacycle-2-methanols to the corresponding lactones is often applied to total synthesis of natural products. It is accomplished by either direct oxidative cleavage reaction using a heavy metal oxidant or multistep conversion. As a practical and environmentally friendly procedure, a direct oxidative cleavage reaction of tetrahydrofuran-2-methanols to the corresponding c-lactones was developed. This new catalytic reaction proceeds with a catalytic amount of 2-iodobenzamide and stoichiometric Oxone (2KHSO5.KHSO4.K2SO4) at room temperature.",

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AU - Yamada, Akihiro

AU - Nambu, Hisanori

AU - Yakura, Takayuki

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Practical and environmentally friendly transformation of tetrahydrofuran- 2-methanols to γ-lactones via oxidative cleavage

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ASJC Scopus 主題領域

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