TY - JOUR
T1 - Palladium(II)-catalyzed stereocontrolled cyclization via hemiacetal intermediates
T2 - Total synthesis of 5-epi-prelactone C
AU - Miyazawa, Masahiro
AU - Narantsetseg, Magsarjav
AU - Yokoyama, Hajime
AU - Yamaguchi, Seiji
AU - Hirai, Yoshiro
PY - 2004/5/1
Y1 - 2004/5/1
N2 - Palladium(II)-catalyzed cyclization of 3,7-dihydroxy-4-methyl-5-octenal derivative was carried out to give 2,3,4,6-tetrasubstituted tetrahydropyran with stereoselective 1,3-chirality transfer in net retention of stereochemistry. The cyclized product was converted into 5-epi-prelactone C.
AB - Palladium(II)-catalyzed cyclization of 3,7-dihydroxy-4-methyl-5-octenal derivative was carried out to give 2,3,4,6-tetrasubstituted tetrahydropyran with stereoselective 1,3-chirality transfer in net retention of stereochemistry. The cyclized product was converted into 5-epi-prelactone C.
UR - http://www.scopus.com/inward/record.url?scp=2442492013&partnerID=8YFLogxK
U2 - 10.3987/COM-04-10034
DO - 10.3987/COM-04-10034
M3 - 学術論文
AN - SCOPUS:2442492013
SN - 0385-5414
VL - 63
SP - 1017
EP - 1021
JO - Heterocycles
JF - Heterocycles
IS - 5
ER -